On the nature of dendrimer cross-linking by ring-closing metathesis

James B. Beil; N. Gabriel Lemcoff; Steven C. Zimmerman

doi:10.1021/ja045885j

On the nature of dendrimer cross-linking by ring-closing metathesis

James B. Beil, N. Gabriel Lemcoff, Steven C. Zimmerman

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

The ring-closing metathesis (RCM) mediated cross-linking of dendrimer 1 and it subunits was examined. Through the combined use of MALDI-MS-TOF, SEC, NMR, and X-ray crystallographic analysis it was shown that the cross-links are formed with the following order of preference: type d ≥ type c > type b ≫ type a.

Original language	English
Pages (from-to)	13576-13577
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	42
DOIs	https://doi.org/10.1021/ja045885j
State	Published - 27 Oct 2004

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja045885j

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title = "On the nature of dendrimer cross-linking by ring-closing metathesis",

abstract = "The ring-closing metathesis (RCM) mediated cross-linking of dendrimer 1 and it subunits was examined. Through the combined use of MALDI-MS-TOF, SEC, NMR, and X-ray crystallographic analysis it was shown that the cross-links are formed with the following order of preference: type d ≥ type c > type b ≫ type a.",

author = "Beil, {James B.} and Lemcoff, {N. Gabriel} and Zimmerman, {Steven C.}",

year = "2004",

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AU - Beil, James B.

AU - Lemcoff, N. Gabriel

AU - Zimmerman, Steven C.

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Y1 - 2004/10/27

N2 - The ring-closing metathesis (RCM) mediated cross-linking of dendrimer 1 and it subunits was examined. Through the combined use of MALDI-MS-TOF, SEC, NMR, and X-ray crystallographic analysis it was shown that the cross-links are formed with the following order of preference: type d ≥ type c > type b ≫ type a.

AB - The ring-closing metathesis (RCM) mediated cross-linking of dendrimer 1 and it subunits was examined. Through the combined use of MALDI-MS-TOF, SEC, NMR, and X-ray crystallographic analysis it was shown that the cross-links are formed with the following order of preference: type d ≥ type c > type b ≫ type a.

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U2 - 10.1021/ja045885j

DO - 10.1021/ja045885j

M3 - Article

AN - SCOPUS:6444229672

SN - 0002-7863

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

On the nature of dendrimer cross-linking by ring-closing metathesis

Abstract

ASJC Scopus subject areas

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