On the nature of dendrimer cross-linking by ring-closing metathesis

James B. Beil, N. Gabriel Lemcoff, Steven C. Zimmerman

Research output: Contribution to journalArticlepeer-review

51 Scopus citations

Abstract

The ring-closing metathesis (RCM) mediated cross-linking of dendrimer 1 and it subunits was examined. Through the combined use of MALDI-MS-TOF, SEC, NMR, and X-ray crystallographic analysis it was shown that the cross-links are formed with the following order of preference: type d ≥ type c > type b ≫ type a.

Original languageEnglish
Pages (from-to)13576-13577
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number42
DOIs
StatePublished - 27 Oct 2004

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