On the role of vibrational excitation in electron transfer reactions with large negative free energies

S. Efrima; M. Bixon

doi:10.1016/0009-2614(74)80325-8

On the role of vibrational excitation in electron transfer reactions with large negative free energies

S. Efrima, M. Bixon

Research output: Contribution to journal › Article › peer-review

172 Scopus citations

Abstract

Apparent disagreement of results of fluorescence quenching with Marcus' theory for outer-sphere electron transfer in polar media is explained, still within the general framework of Marcus' theory, by including vibrational transitions.

Original language	English
Pages (from-to)	34-37
Number of pages	4
Journal	Chemical Physics Letters
Volume	25
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(74)80325-8
State	Published - 1 Mar 1974
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1016/0009-2614(74)80325-8

Cite this

@article{8f9511f921b045f39cc9511a2dd848f0,

title = "On the role of vibrational excitation in electron transfer reactions with large negative free energies",

abstract = "Apparent disagreement of results of fluorescence quenching with Marcus' theory for outer-sphere electron transfer in polar media is explained, still within the general framework of Marcus' theory, by including vibrational transitions.",

author = "S. Efrima and M. Bixon",

year = "1974",

month = mar,

day = "1",

doi = "10.1016/0009-2614(74)80325-8",

language = "English",

volume = "25",

pages = "34--37",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - On the role of vibrational excitation in electron transfer reactions with large negative free energies

AU - Efrima, S.

AU - Bixon, M.

PY - 1974/3/1

Y1 - 1974/3/1

N2 - Apparent disagreement of results of fluorescence quenching with Marcus' theory for outer-sphere electron transfer in polar media is explained, still within the general framework of Marcus' theory, by including vibrational transitions.

AB - Apparent disagreement of results of fluorescence quenching with Marcus' theory for outer-sphere electron transfer in polar media is explained, still within the general framework of Marcus' theory, by including vibrational transitions.

UR - http://www.scopus.com/inward/record.url?scp=4244042256&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(74)80325-8

DO - 10.1016/0009-2614(74)80325-8

M3 - Article

AN - SCOPUS:4244042256

SN - 0009-2614

VL - 25

SP - 34

EP - 37

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

On the role of vibrational excitation in electron transfer reactions with large negative free energies

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this