On the Suppression-of-Junction-Fluctuations Parameter in Flory's Network Theory

M. Gottlieb; C. W. Macosko

doi:10.1021/ma00230a062

On the Suppression-of-Junction-Fluctuations Parameter in Flory's Network Theory

M. Gottlieb, C. W. Macosko

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The concept of suppression of junction fluctuations in polymer networks is quantified by means of κ in Flory's recent network elasticity theory. The same concept is also measured by the h parameter in Dossin and Graessley's expression for the small-strain modulus. In this work an analytical relationship between these two physically related parameters is obtained for the case of a perfect, incompressible, unswollen network.

Original language	English
Pages (from-to)	535-537
Number of pages	3
Journal	Macromolecules
Volume	15
Issue number	2
DOIs	https://doi.org/10.1021/ma00230a062
State	Published - 1 Jan 1982

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma00230a062

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title = "On the Suppression-of-Junction-Fluctuations Parameter in Flory's Network Theory",

abstract = "The concept of suppression of junction fluctuations in polymer networks is quantified by means of κ in Flory's recent network elasticity theory. The same concept is also measured by the h parameter in Dossin and Graessley's expression for the small-strain modulus. In this work an analytical relationship between these two physically related parameters is obtained for the case of a perfect, incompressible, unswollen network.",

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N2 - The concept of suppression of junction fluctuations in polymer networks is quantified by means of κ in Flory's recent network elasticity theory. The same concept is also measured by the h parameter in Dossin and Graessley's expression for the small-strain modulus. In this work an analytical relationship between these two physically related parameters is obtained for the case of a perfect, incompressible, unswollen network.

AB - The concept of suppression of junction fluctuations in polymer networks is quantified by means of κ in Flory's recent network elasticity theory. The same concept is also measured by the h parameter in Dossin and Graessley's expression for the small-strain modulus. In this work an analytical relationship between these two physically related parameters is obtained for the case of a perfect, incompressible, unswollen network.

UR - https://www.scopus.com/pages/publications/0009268534

U2 - 10.1021/ma00230a062

DO - 10.1021/ma00230a062

M3 - Article

AN - SCOPUS:0009268534

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EP - 537

JO - Macromolecules

JF - Macromolecules

IS - 2

ER -

On the Suppression-of-Junction-Fluctuations Parameter in Flory's Network Theory

Abstract

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