Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

A. V. Palii; B. S. Tsukerblat; M. Verdaguer

doi:10.1063/1.1510120

Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

A. V. Palii, B. S. Tsukerblat, M. Verdaguer

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C₄ easy axis of magnetization.

Original language	English
Pages (from-to)	7896-7905
Number of pages	10
Journal	Journal of Chemical Physics
Volume	117
Issue number	17
DOIs	https://doi.org/10.1063/1.1510120
State	Published - 1 Nov 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1510120

Cite this

@article{9ce61f03890249b5a2978c784f91df89,

title = "Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer",

abstract = "The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C4 easy axis of magnetization.",

author = "Palii, {A. V.} and Tsukerblat, {B. S.} and M. Verdaguer",

year = "2002",

month = nov,

day = "1",

doi = "10.1063/1.1510120",

language = "English",

volume = "117",

pages = "7896--7905",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "17",

}

TY - JOUR

T1 - Orbitally dependent kinetic exchange in a heterobimetallic pair

T2 - Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

AU - Palii, A. V.

AU - Tsukerblat, B. S.

AU - Verdaguer, M.

PY - 2002/11/1

Y1 - 2002/11/1

N2 - The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C4 easy axis of magnetization.

AB - The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C4 easy axis of magnetization.

UR - http://www.scopus.com/inward/record.url?scp=0036850795&partnerID=8YFLogxK

U2 - 10.1063/1.1510120

DO - 10.1063/1.1510120

M3 - Article

AN - SCOPUS:0036850795

SN - 0021-9606

VL - 117

SP - 7896

EP - 7905

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 17

ER -

Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this