Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

A. V. Palii; B. S. Tsukerblat; M. Verdaguer

doi:10.1063/1.1510120

Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

A. V. Palii
, B. S. Tsukerblat
, M. Verdaguer

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C₄ easy axis of magnetization.

Original language	English
Pages (from-to)	7896-7905
Number of pages	10
Journal	Journal of Chemical Physics
Volume	117
Issue number	17
DOIs	https://doi.org/10.1063/1.1510120
State	Published - 1 Nov 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer",

abstract = "The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C4 easy axis of magnetization.",

author = "Palii, \{A. V.\} and Tsukerblat, \{B. S.\} and M. Verdaguer",

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T2 - Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

AU - Palii, A. V.

AU - Tsukerblat, B. S.

AU - Verdaguer, M.

PY - 2002/11/1

Y1 - 2002/11/1

N2 - The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C4 easy axis of magnetization.

AB - The kinetic exchange interaction in the cynide-bridged heterobinuclear dimers involving orbitally degenerate transition metal ions was discussed. The bioctahedral cyanide-bridged Cr(III)Fe(II) dimer, which exhibited new quantitative and qualitative features of the orbitally dependent exchange, was considered. The analysis suggested that the kinetic exchange in the cyanide-bridged Cr(III)Fe(II) pair leads to the ferromagnetic spin alignment exhibiting at the same time strong axial magnetic anisotropy with C4 easy axis of magnetization.

UR - https://www.scopus.com/pages/publications/0036850795

U2 - 10.1063/1.1510120

DO - 10.1063/1.1510120

M3 - Article

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SN - 0021-9606

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 17

ER -

Orbitally dependent kinetic exchange in a heterobimetallic pair: Ferromagnetic spin alignment and magnetic anisotropy in the cyano-bridged Cr(III)Fe(II) dimer

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