Organic-inorganic hybrid perovskite (C6H5(CH2)2NH3)2CdCl4: Synthesis, structural and thermal properties

S. Kassou; A. Kaiba; P. Guionneau; A. Belaaraj

doi:10.1134/S0022476616040168

Organic-inorganic hybrid perovskite (C₆H₅(CH₂)₂NH₃)₂CdCl₄: Synthesis, structural and thermal properties

S. Kassou
, A. Kaiba
, P. Guionneau
, A. Belaaraj

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The present research work reports the study on crystal structure, vibrational spectroscopy and thermal analysis of organic-inorganic hybrid compound (C₆H₅(CH₂)₂NH₃)₂CdCl₄. Single crystals of bis(phenethylammonium)tetrachlorocadmate (C₆H₅(CH₂)₂NH₃)₂CdCl₄ (PEA–Cd) were obtained by diffusion at room temperature. This compound crystallizes in the orthorhombic space group C2cb with unit cell parameters a = 7.4444(2) Å, b = 38.8965(3) Å, c = 7.3737(2) Å and Z = 4. Single crystal structure has been solved and refined to R = 0.036 and wR = 0.092. The structure consists of an extended [CdCl₄]^2– network and two [C₆H₅(CH₂)₂NH₃]⁺ cations to form a two-dimensional perovskite system. The infrared (IR) spectrum of the title compound was recorded at room temperature. Differential scanning calorimetry (DSC) was used to investigate the phase transition; this compound exhibits a reversible single solid-solid phase transition.

Original language	English
Pages (from-to)	737-743
Number of pages	7
Journal	Journal of Structural Chemistry
Volume	57
Issue number	4
DOIs	https://doi.org/10.1134/S0022476616040168
State	Published - 1 Jul 2016
Externally published	Yes

Keywords

differential scanning calorimetry (DSC)
layered perovskite
organic-inorganic hybrid
single crystal
structural phase transition

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1134/S0022476616040168

Cite this

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title = "Organic-inorganic hybrid perovskite (C6H5(CH2)2NH3)2CdCl4: Synthesis, structural and thermal properties",

abstract = "The present research work reports the study on crystal structure, vibrational spectroscopy and thermal analysis of organic-inorganic hybrid compound (C6H5(CH2)2NH3)2CdCl4. Single crystals of bis(phenethylammonium)tetrachlorocadmate (C6H5(CH2)2NH3)2CdCl4 (PEA–Cd) were obtained by diffusion at room temperature. This compound crystallizes in the orthorhombic space group C2cb with unit cell parameters a = 7.4444(2) {\AA}, b = 38.8965(3) {\AA}, c = 7.3737(2) {\AA} and Z = 4. Single crystal structure has been solved and refined to R = 0.036 and wR = 0.092. The structure consists of an extended [CdCl4]2– network and two [C6H5(CH2)2NH3]+ cations to form a two-dimensional perovskite system. The infrared (IR) spectrum of the title compound was recorded at room temperature. Differential scanning calorimetry (DSC) was used to investigate the phase transition; this compound exhibits a reversible single solid-solid phase transition.",

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author = "S. Kassou and A. Kaiba and P. Guionneau and A. Belaaraj",

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T2 - Synthesis, structural and thermal properties

AU - Kassou, S.

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AU - Guionneau, P.

AU - Belaaraj, A.

PY - 2016/7/1

Y1 - 2016/7/1

N2 - The present research work reports the study on crystal structure, vibrational spectroscopy and thermal analysis of organic-inorganic hybrid compound (C6H5(CH2)2NH3)2CdCl4. Single crystals of bis(phenethylammonium)tetrachlorocadmate (C6H5(CH2)2NH3)2CdCl4 (PEA–Cd) were obtained by diffusion at room temperature. This compound crystallizes in the orthorhombic space group C2cb with unit cell parameters a = 7.4444(2) Å, b = 38.8965(3) Å, c = 7.3737(2) Å and Z = 4. Single crystal structure has been solved and refined to R = 0.036 and wR = 0.092. The structure consists of an extended [CdCl4]2– network and two [C6H5(CH2)2NH3]+ cations to form a two-dimensional perovskite system. The infrared (IR) spectrum of the title compound was recorded at room temperature. Differential scanning calorimetry (DSC) was used to investigate the phase transition; this compound exhibits a reversible single solid-solid phase transition.

AB - The present research work reports the study on crystal structure, vibrational spectroscopy and thermal analysis of organic-inorganic hybrid compound (C6H5(CH2)2NH3)2CdCl4. Single crystals of bis(phenethylammonium)tetrachlorocadmate (C6H5(CH2)2NH3)2CdCl4 (PEA–Cd) were obtained by diffusion at room temperature. This compound crystallizes in the orthorhombic space group C2cb with unit cell parameters a = 7.4444(2) Å, b = 38.8965(3) Å, c = 7.3737(2) Å and Z = 4. Single crystal structure has been solved and refined to R = 0.036 and wR = 0.092. The structure consists of an extended [CdCl4]2– network and two [C6H5(CH2)2NH3]+ cations to form a two-dimensional perovskite system. The infrared (IR) spectrum of the title compound was recorded at room temperature. Differential scanning calorimetry (DSC) was used to investigate the phase transition; this compound exhibits a reversible single solid-solid phase transition.

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