Organotellurium halides: New ligands for transition metal complexes

Yury Torubaev; Alexander Pasynskii; Pradeep Mathur

doi:10.1016/j.ccr.2011.11.011

Organotellurium halides: New ligands for transition metal complexes

Yury Torubaev, Alexander Pasynskii, Pradeep Mathur

Research output: Contribution to journal › Review article › peer-review

25 Scopus citations

Abstract

This review summarizes recent advances in the coordination chemistry of organotellurium halides with an emphasis on the special features of the coordination patterns of the aryltellurium halides (ArTeX; X = Br, I) in transition metal carbonyl complexes (Fe, Co, Mn, Re, Ru). Unusual shortening of metal-tellurium bonds and inter- and intramolecular X → Te secondary interactions are observed.

Original language	English
Pages (from-to)	709-721
Number of pages	13
Journal	Coordination Chemistry Reviews
Volume	256
Issue number	5-8
DOIs	https://doi.org/10.1016/j.ccr.2011.11.011
State	Published - 1 Mar 2012
Externally published	Yes

Keywords

Chalcohalides
Hypervalent
Organotellurium
Secondary bond
Tellurenyl
Tellurides
Tellurohalides
Transition metal complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ccr.2011.11.011

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title = "Organotellurium halides: New ligands for transition metal complexes",

abstract = "This review summarizes recent advances in the coordination chemistry of organotellurium halides with an emphasis on the special features of the coordination patterns of the aryltellurium halides (ArTeX; X = Br, I) in transition metal carbonyl complexes (Fe, Co, Mn, Re, Ru). Unusual shortening of metal-tellurium bonds and inter- and intramolecular X → Te secondary interactions are observed.",

keywords = "Chalcohalides, Hypervalent, Organotellurium, Secondary bond, Tellurenyl, Tellurides, Tellurohalides, Transition metal complexes",

author = "Yury Torubaev and Alexander Pasynskii and Pradeep Mathur",

note = "Funding Information: We gratefully acknowledge the financial support from the Department of Science and Technology, Government of India , the Council for the President Grants (MD 7122.2012.3) and Russian Foundation for Basic Research (grant 09-03-00961 , 12-03-00860 ).",

year = "2012",

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doi = "10.1016/j.ccr.2011.11.011",

language = "English",

volume = "256",

pages = "709--721",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

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number = "5-8",

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TY - JOUR

T1 - Organotellurium halides

T2 - New ligands for transition metal complexes

AU - Torubaev, Yury

AU - Pasynskii, Alexander

AU - Mathur, Pradeep

N1 - Funding Information: We gratefully acknowledge the financial support from the Department of Science and Technology, Government of India , the Council for the President Grants (MD 7122.2012.3) and Russian Foundation for Basic Research (grant 09-03-00961 , 12-03-00860 ).

PY - 2012/3/1

Y1 - 2012/3/1

N2 - This review summarizes recent advances in the coordination chemistry of organotellurium halides with an emphasis on the special features of the coordination patterns of the aryltellurium halides (ArTeX; X = Br, I) in transition metal carbonyl complexes (Fe, Co, Mn, Re, Ru). Unusual shortening of metal-tellurium bonds and inter- and intramolecular X → Te secondary interactions are observed.

AB - This review summarizes recent advances in the coordination chemistry of organotellurium halides with an emphasis on the special features of the coordination patterns of the aryltellurium halides (ArTeX; X = Br, I) in transition metal carbonyl complexes (Fe, Co, Mn, Re, Ru). Unusual shortening of metal-tellurium bonds and inter- and intramolecular X → Te secondary interactions are observed.

KW - Chalcohalides

KW - Hypervalent

KW - Organotellurium

KW - Secondary bond

KW - Tellurenyl

KW - Tellurides

KW - Tellurohalides

KW - Transition metal complexes

UR - http://www.scopus.com/inward/record.url?scp=84857439668&partnerID=8YFLogxK

U2 - 10.1016/j.ccr.2011.11.011

DO - 10.1016/j.ccr.2011.11.011

M3 - Review article

AN - SCOPUS:84857439668

SN - 0010-8545

VL - 256

SP - 709

EP - 721

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 5-8

ER -

Organotellurium halides: New ligands for transition metal complexes

Abstract

Keywords

ASJC Scopus subject areas

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