Oxidation of ferrocene and 1,1'-ferrocene triselenide by bromine and phenyltellurium tribromide

Yu V. Torubaev; A. V. Pavlova; A. A. Pasynskii; Abhinav Raghuvanshi; Mobin M. Shaikh

doi:10.1134/S1070328415100085

Oxidation of ferrocene and 1,1'-ferrocene triselenide by bromine and phenyltellurium tribromide

Yu V. Torubaev, A. V. Pavlova, A. A. Pasynskii, Abhinav Raghuvanshi, Mobin M. Shaikh

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The reaction of 1,1'-ferrocene triselenide, Fe(C₅H₄)₂Se₃ (I), with bromine or phenyltellurium tribromide, PhTeBr₃, involves the oxidation of compound I to form salts [Fe(C₅H₄)₂Se₃]⁺FeBr ₄ ^- (II) and [Fe(C₅H₄)₂Se₃]⁺PhTeBr ₄ ^- (III), respectively. Depending on the crystallization conditions, the reaction of ferrocene with PhTeBr₃ affords salt [Fc]⁺[PhTeBr₄]^- (IVa), its solvate with benzene{[Fc]⁺[PhTeBr₄]^-}₂ · C₆H₆ (IVb), or etherate [Fc]⁺[Ph₂Te₂Br₆OH]^- · 0.5(C₂H₅)₂O (V). The structures of compounds II, III, IVa, IVb, and V are determined by X-ray diffraction analysis (CIF files CCDC 1054193 (II), 1054192 (III), 1054194 (IVa), 1054195 (IVb), and 1054196 (V)).

Original language	English
Pages (from-to)	638-643
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	41
Issue number	10
DOIs	https://doi.org/10.1134/S1070328415100085
State	Published - 1 Oct 2015
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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title = "Oxidation of ferrocene and 1,1'-ferrocene triselenide by bromine and phenyltellurium tribromide",

abstract = "The reaction of 1,1'-ferrocene triselenide, Fe(C5H4)2Se3 (I), with bromine or phenyltellurium tribromide, PhTeBr3, involves the oxidation of compound I to form salts [Fe(C5H4)2Se3]+FeBr 4 - (II) and [Fe(C5H4)2Se3]+PhTeBr 4 - (III), respectively. Depending on the crystallization conditions, the reaction of ferrocene with PhTeBr3 affords salt [Fc]+[PhTeBr4]- (IVa), its solvate with benzene{[Fc]+[PhTeBr4]-}2 · C6H6 (IVb), or etherate [Fc]+[Ph2Te2Br6OH]- · 0.5(C2H5)2O (V). The structures of compounds II, III, IVa, IVb, and V are determined by X-ray diffraction analysis (CIF files CCDC 1054193 (II), 1054192 (III), 1054194 (IVa), 1054195 (IVb), and 1054196 (V)).",

author = "Torubaev, {Yu V.} and Pavlova, {A. V.} and Pasynskii, {A. A.} and Abhinav Raghuvanshi and Shaikh, {Mobin M.}",

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T1 - Oxidation of ferrocene and 1,1'-ferrocene triselenide by bromine and phenyltellurium tribromide

AU - Torubaev, Yu V.

AU - Pavlova, A. V.

AU - Pasynskii, A. A.

AU - Raghuvanshi, Abhinav

AU - Shaikh, Mobin M.

PY - 2015/10/1

Y1 - 2015/10/1

N2 - The reaction of 1,1'-ferrocene triselenide, Fe(C5H4)2Se3 (I), with bromine or phenyltellurium tribromide, PhTeBr3, involves the oxidation of compound I to form salts [Fe(C5H4)2Se3]+FeBr 4 - (II) and [Fe(C5H4)2Se3]+PhTeBr 4 - (III), respectively. Depending on the crystallization conditions, the reaction of ferrocene with PhTeBr3 affords salt [Fc]+[PhTeBr4]- (IVa), its solvate with benzene{[Fc]+[PhTeBr4]-}2 · C6H6 (IVb), or etherate [Fc]+[Ph2Te2Br6OH]- · 0.5(C2H5)2O (V). The structures of compounds II, III, IVa, IVb, and V are determined by X-ray diffraction analysis (CIF files CCDC 1054193 (II), 1054192 (III), 1054194 (IVa), 1054195 (IVb), and 1054196 (V)).

AB - The reaction of 1,1'-ferrocene triselenide, Fe(C5H4)2Se3 (I), with bromine or phenyltellurium tribromide, PhTeBr3, involves the oxidation of compound I to form salts [Fe(C5H4)2Se3]+FeBr 4 - (II) and [Fe(C5H4)2Se3]+PhTeBr 4 - (III), respectively. Depending on the crystallization conditions, the reaction of ferrocene with PhTeBr3 affords salt [Fc]+[PhTeBr4]- (IVa), its solvate with benzene{[Fc]+[PhTeBr4]-}2 · C6H6 (IVb), or etherate [Fc]+[Ph2Te2Br6OH]- · 0.5(C2H5)2O (V). The structures of compounds II, III, IVa, IVb, and V are determined by X-ray diffraction analysis (CIF files CCDC 1054193 (II), 1054192 (III), 1054194 (IVa), 1054195 (IVb), and 1054196 (V)).

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Oxidation of ferrocene and 1,1'-ferrocene triselenide by bromine and phenyltellurium tribromide

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