Oxidative addition of the Mo-Cl bond to the Pt0 complex. Synthesis and structure of Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl

A. A. Pasynskii, I. V. Skabitskii, Yu V. Torubaev, S. S. Shapovalov

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

A reaction of Cp?Mo(CO)3Cl(Cp? = MeC5H4) with (PPh3)2Pt(C2Ph2) gave the heterometallic cluster Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl (I) as the sole product. According to X-ray diffraction data, complex I contains single Pt-Mo bonds (2.7962(5) and 2.7699(5) Å) but no Pt-Pt bond (Pt...Pt 2.9746(3) Å). The coordinated diphenylacetylene molecule forms two Pt-C σ-bonds (2.054(6) and 2.083(5) Å) and a π-bond to the Mo atom (Mo-C 2.265(6) and 2.272(5) Å; C?C 1.387(8) Å).

Original languageEnglish
Pages (from-to)401-404
Number of pages4
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume35
Issue number6
DOIs
StatePublished - 1 Jun 2009
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering

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