Abstract
A reaction of Cp?Mo(CO)3Cl(Cp? = MeC5H4) with (PPh3)2Pt(C2Ph2) gave the heterometallic cluster Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl (I) as the sole product. According to X-ray diffraction data, complex I contains single Pt-Mo bonds (2.7962(5) and 2.7699(5) Å) but no Pt-Pt bond (Pt...Pt 2.9746(3) Å). The coordinated diphenylacetylene molecule forms two Pt-C σ-bonds (2.054(6) and 2.083(5) Å) and a π-bond to the Mo atom (Mo-C 2.265(6) and 2.272(5) Å; C?C 1.387(8) Å).
Original language | English |
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Pages (from-to) | 401-404 |
Number of pages | 4 |
Journal | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
Volume | 35 |
Issue number | 6 |
DOIs | |
State | Published - 1 Jun 2009 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
- General Chemical Engineering