Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family

L. Čapek; J. Adam; T. Grygar; R. Bulánek; L. Vradman; G. Košová-Kučerová; P. Čičmanec; P. Knotek

doi:10.1016/j.apcata.2008.03.003

Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family

L. Čapek, J. Adam, T. Grygar, R. Bulánek, L. Vradman, G. Košová-Kučerová, P. Čičmanec, P. Knotek

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

The contribution deals with mesoporous materials of M41S family post-synthetically dopped with vanadium oxo-species. The performance of V-HMS, V-MCM-41 and V-SBA-15 catalysts with varying vanadium loadings was studied in oxidative dehydrogenation (ODH) of ethane. The objectives of this study were to determine a possible activity of vanadium species supported on mesoporous materials of M41S family and to optimize reaction conditions. We contribute to the understanding of the relationship between the activity of vanadium species in ODH of ethane and its distribution. Vanadium-based catalysts were analyzed by UV-vis spectroscopy, voltammetry of microparticles (VMP), and nitrogen adsorption (determination of specific surface area). The most active catalysts contained 2-4.5 wt.% V finely dispersed over mesoporous support in the form of isolated monomeric and oligomeric vanadium species. V-HMS, V-MCM-41 and V-SBA-15 exhibited comparable activity in ODH of ethane.

Original language	English
Pages (from-to)	99-106
Number of pages	8
Journal	Applied Catalysis A: General
Volume	342
Issue number	1-2
DOIs	https://doi.org/10.1016/j.apcata.2008.03.003
State	Published - 30 Jun 2008

Keywords

Ethane
Mesoporous materials
Oxidative dehydrogenation
Vanadium

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

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10.1016/j.apcata.2008.03.003

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title = "Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family",

abstract = "The contribution deals with mesoporous materials of M41S family post-synthetically dopped with vanadium oxo-species. The performance of V-HMS, V-MCM-41 and V-SBA-15 catalysts with varying vanadium loadings was studied in oxidative dehydrogenation (ODH) of ethane. The objectives of this study were to determine a possible activity of vanadium species supported on mesoporous materials of M41S family and to optimize reaction conditions. We contribute to the understanding of the relationship between the activity of vanadium species in ODH of ethane and its distribution. Vanadium-based catalysts were analyzed by UV-vis spectroscopy, voltammetry of microparticles (VMP), and nitrogen adsorption (determination of specific surface area). The most active catalysts contained 2-4.5 wt.% V finely dispersed over mesoporous support in the form of isolated monomeric and oligomeric vanadium species. V-HMS, V-MCM-41 and V-SBA-15 exhibited comparable activity in ODH of ethane.",

keywords = "Ethane, Mesoporous materials, Oxidative dehydrogenation, Vanadium",

author = "L. {\v C}apek and J. Adam and T. Grygar and R. Bul{\'a}nek and L. Vradman and G. Ko{\v s}ov{\'a}-Ku{\v c}erov{\'a} and P. {\v C}i{\v c}manec and P. Knotek",

note = "Funding Information: The authors gratefully thank to the Grant Agency of Czech Republic for financial support (No. 104/07/P038) and Ministry of Education, Youth and Sports (MSM0021627501).",

year = "2008",

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doi = "10.1016/j.apcata.2008.03.003",

language = "English",

volume = "342",

pages = "99--106",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family

AU - Čapek, L.

AU - Adam, J.

AU - Grygar, T.

AU - Bulánek, R.

AU - Vradman, L.

AU - Košová-Kučerová, G.

AU - Čičmanec, P.

AU - Knotek, P.

N1 - Funding Information: The authors gratefully thank to the Grant Agency of Czech Republic for financial support (No. 104/07/P038) and Ministry of Education, Youth and Sports (MSM0021627501).

PY - 2008/6/30

Y1 - 2008/6/30

N2 - The contribution deals with mesoporous materials of M41S family post-synthetically dopped with vanadium oxo-species. The performance of V-HMS, V-MCM-41 and V-SBA-15 catalysts with varying vanadium loadings was studied in oxidative dehydrogenation (ODH) of ethane. The objectives of this study were to determine a possible activity of vanadium species supported on mesoporous materials of M41S family and to optimize reaction conditions. We contribute to the understanding of the relationship between the activity of vanadium species in ODH of ethane and its distribution. Vanadium-based catalysts were analyzed by UV-vis spectroscopy, voltammetry of microparticles (VMP), and nitrogen adsorption (determination of specific surface area). The most active catalysts contained 2-4.5 wt.% V finely dispersed over mesoporous support in the form of isolated monomeric and oligomeric vanadium species. V-HMS, V-MCM-41 and V-SBA-15 exhibited comparable activity in ODH of ethane.

AB - The contribution deals with mesoporous materials of M41S family post-synthetically dopped with vanadium oxo-species. The performance of V-HMS, V-MCM-41 and V-SBA-15 catalysts with varying vanadium loadings was studied in oxidative dehydrogenation (ODH) of ethane. The objectives of this study were to determine a possible activity of vanadium species supported on mesoporous materials of M41S family and to optimize reaction conditions. We contribute to the understanding of the relationship between the activity of vanadium species in ODH of ethane and its distribution. Vanadium-based catalysts were analyzed by UV-vis spectroscopy, voltammetry of microparticles (VMP), and nitrogen adsorption (determination of specific surface area). The most active catalysts contained 2-4.5 wt.% V finely dispersed over mesoporous support in the form of isolated monomeric and oligomeric vanadium species. V-HMS, V-MCM-41 and V-SBA-15 exhibited comparable activity in ODH of ethane.

KW - Ethane

KW - Mesoporous materials

KW - Oxidative dehydrogenation

KW - Vanadium

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Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family

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Keywords

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