Packing analysis and the crystal chemistry of 2,5-dibenzylidenecyclopent-3-ene-1-one. Rationale for a non-topochemical solid-state reaction

Jagarlapudi A.R.P. Sarma; Joel Bernstein

doi:10.1007/BF00999702

Packing analysis and the crystal chemistry of 2,5-dibenzylidenecyclopent-3-ene-1-one. Rationale for a non-topochemical solid-state reaction

Jagarlapudi A.R.P. Sarma, Joel Bernstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The molecular and crystal structure of 2,5-dibenzylidenecyclopent-3-ene-1-one has been studied in detail to explain the formation of a non-topochemical pseudo-mirror-symmetric dimer upon photoirradiation. Packing energy calculations, analysis of the thermal motion, and lattice energy calculations are employed to analyse and understand the observed dimerization reaction, crystal structure, and crystal properties.

Original language	English
Pages (from-to)	103-116
Number of pages	14
Journal	Molecular Engineering
Volume	2
Issue number	2
DOIs	https://doi.org/10.1007/BF00999702
State	Published - 1 Jun 1992

Keywords

Non-topochemical reaction
crystal structure
disorder
lattice energy calculations
thermal motion analysis

ASJC Scopus subject areas

Biochemistry

Access to Document

10.1007/BF00999702

Cite this

@article{2a7ebc1c3ef74bbcbb7ed178ddb8f3b1,

title = "Packing analysis and the crystal chemistry of 2,5-dibenzylidenecyclopent-3-ene-1-one. Rationale for a non-topochemical solid-state reaction",

abstract = "The molecular and crystal structure of 2,5-dibenzylidenecyclopent-3-ene-1-one has been studied in detail to explain the formation of a non-topochemical pseudo-mirror-symmetric dimer upon photoirradiation. Packing energy calculations, analysis of the thermal motion, and lattice energy calculations are employed to analyse and understand the observed dimerization reaction, crystal structure, and crystal properties.",

keywords = "Non-topochemical reaction, crystal structure, disorder, lattice energy calculations, thermal motion analysis",

author = "Sarma, {Jagarlapudi A.R.P.} and Joel Bernstein",

year = "1992",

month = jun,

day = "1",

doi = "10.1007/BF00999702",

language = "English",

volume = "2",

pages = "103--116",

journal = "Molecular Engineering",

issn = "0925-5125",

number = "2",

}

TY - JOUR

T1 - Packing analysis and the crystal chemistry of 2,5-dibenzylidenecyclopent-3-ene-1-one. Rationale for a non-topochemical solid-state reaction

AU - Sarma, Jagarlapudi A.R.P.

AU - Bernstein, Joel

PY - 1992/6/1

Y1 - 1992/6/1

N2 - The molecular and crystal structure of 2,5-dibenzylidenecyclopent-3-ene-1-one has been studied in detail to explain the formation of a non-topochemical pseudo-mirror-symmetric dimer upon photoirradiation. Packing energy calculations, analysis of the thermal motion, and lattice energy calculations are employed to analyse and understand the observed dimerization reaction, crystal structure, and crystal properties.

AB - The molecular and crystal structure of 2,5-dibenzylidenecyclopent-3-ene-1-one has been studied in detail to explain the formation of a non-topochemical pseudo-mirror-symmetric dimer upon photoirradiation. Packing energy calculations, analysis of the thermal motion, and lattice energy calculations are employed to analyse and understand the observed dimerization reaction, crystal structure, and crystal properties.

KW - Non-topochemical reaction

KW - crystal structure

KW - disorder

KW - lattice energy calculations

KW - thermal motion analysis

UR - http://www.scopus.com/inward/record.url?scp=0007172167&partnerID=8YFLogxK

U2 - 10.1007/BF00999702

DO - 10.1007/BF00999702

M3 - Article

AN - SCOPUS:0007172167

SN - 0925-5125

VL - 2

SP - 103

EP - 116

JO - Molecular Engineering

JF - Molecular Engineering

IS - 2

ER -

Packing analysis and the crystal chemistry of 2,5-dibenzylidenecyclopent-3-ene-1-one. Rationale for a non-topochemical solid-state reaction

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this