Abstract
Chemical engines process mass flows to convert differences in chemical potential into work - the analog of heat engines processing heat flows to generate work from temperature differences. For isothermal endoreversible chemical engines constrained to finite-time operation - examples of which include mass exchangers, electrochemical, photochemical, and solid-state devices: (i) optimal cycle types for maximizing average power output, (ii) upper bounds on power production, and (iii) sensitivity of these results to mass-transfer law, illustrated for linear and diffusive behavior, are derived.
Original language | English |
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Pages (from-to) | 5303-5309 |
Number of pages | 7 |
Journal | Journal of Applied Physics |
Volume | 74 |
Issue number | 9 |
DOIs | |
State | Published - 1 Dec 1993 |
ASJC Scopus subject areas
- Physics and Astronomy (all)