Permeability and selectivity of reverse osmosis membranes: Correlation to swelling revisited

Emil Dražević, Krešimir Košutić, Viatcheslav Freger

Research output: Contribution to journalArticlepeer-review

92 Scopus citations

Abstract

Membrane swelling governs both rejection of solutes and permeability of polymeric membranes, however very few data have been available on swelling in water of salt-rejecting reverse osmosis (RO) membranes. This study assesses swelling, thickness and their relation to water permeability for four commercial polyamide (PA) RO membranes (SWC4+, ESPA1, XLE and BW30) using atomic force microscopy (AFM) and attenuated total reflection Fourier transform IR spectroscopy (ATR-FTIR). ATR-FTIR offered a significantly improved estimate of the actual barrier thickness of PA, given AFM is biased by porosity ("fluffy parts") or wiggling of the active layer or presence of a coating layer. Thus obtained intrinsic permeability (permeability times thickness) and selectivity of aromatic polyamides plotted versus swelling falls well on a general trend, along with previously reported data on several common materials showing RO and NF selectivity. The observed general trend may be rationalized by viewing the polymers as a random composite medium containing molecularly small pores. The results suggest that the combination of a rigid low dielectric matrix, limiting the pore size, with multiple hydrophilic H-bonding sites may be a common feature of RO/NF membranes, allowing both high permeability and selectivity.

Original languageEnglish
Pages (from-to)444-452
Number of pages9
JournalWater Research
Volume49
DOIs
StatePublished - 1 Feb 2014
Externally publishedYes

Keywords

  • Dielectric exclusion
  • Nanofiltration
  • Permeability
  • Reverse osmosis
  • Salt rejection
  • Swelling

ASJC Scopus subject areas

  • Environmental Engineering
  • Civil and Structural Engineering
  • Ecological Modeling
  • Water Science and Technology
  • Waste Management and Disposal
  • Pollution

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