TY - JOUR
T1 - Phase equilibria in the systems 1-hexene + benzene and 1-hexene + ethyl 1,1-dimethylethyl ether + benzene at 94.00 kPa
AU - Segura, Hugo
AU - Wisniak, Jaime
AU - Galindo, Graciela
AU - Reich, Ricardo
PY - 2001/5/1
Y1 - 2001/5/1
N2 - Consistent vapor-liquid equilibria data at 94.00 kPa have been determined for the ternary system 1-hexene + ethyl 1,1-dimethylethyl ether + benzene and for its constituent binary 1-hexene + benzene, in the temperature range 334-351 K. According to the experimental results, the systems exhibit slight positive deviations from ideal behavior and no azeotrope is present. The VLE data have been correlated with the mole fraction using the Redlich-Kister, Wilson, NRTL, UNIQUAC, and Tamir relations. These models, in addition to UNIFAC, allow good prediction of the VLE properties of the ternary system from those of the pertinent binary systems.
AB - Consistent vapor-liquid equilibria data at 94.00 kPa have been determined for the ternary system 1-hexene + ethyl 1,1-dimethylethyl ether + benzene and for its constituent binary 1-hexene + benzene, in the temperature range 334-351 K. According to the experimental results, the systems exhibit slight positive deviations from ideal behavior and no azeotrope is present. The VLE data have been correlated with the mole fraction using the Redlich-Kister, Wilson, NRTL, UNIQUAC, and Tamir relations. These models, in addition to UNIFAC, allow good prediction of the VLE properties of the ternary system from those of the pertinent binary systems.
UR - http://www.scopus.com/inward/record.url?scp=0035335750&partnerID=8YFLogxK
U2 - 10.1021/je000165n
DO - 10.1021/je000165n
M3 - Article
AN - SCOPUS:0035335750
SN - 0021-9568
VL - 46
SP - 506
EP - 510
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 3
ER -