Phase equilibria in the ternary system methyl 1,1-dimethylethyl ether + oxolane + heptane

Jaime Wisniak; Gabriela Embon; Ran Shafir

doi:10.1080/00319109808035919

Phase equilibria in the ternary system methyl 1,1-dimethylethyl ether + oxolane + heptane

Jaime Wisniak, Gabriela Embon, Ran Shafir

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Vapor-liquid equilibrium at 94 kPa has been determined for the ternary system methyl 1,1-dimethylethyl ether (MTBE) + oxolane + heptane. The system deviates positively from ideality and no azeotrope is present The ternary activity coefficients and the boiling points of the system have been correlated with the composition using the Redlich-Kister, Wilson, NRTL, UNIQUAC, UNIFAC, and Wisniak-Tamir relations. Most of the models allow a good prediction of the activity coefficients of the ternary system from those of the pertinent binary systems.

Original language	English
Pages (from-to)	37-51
Number of pages	15
Journal	Physics and Chemistry of Liquids
Volume	36
Issue number	1
DOIs	https://doi.org/10.1080/00319109808035919
State	Published - 1 Jan 1998

Keywords

Activity coefficients
Ternary systems
Vapor-liquid equilibrium

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Physical and Theoretical Chemistry
Materials Chemistry

Access to Document

10.1080/00319109808035919

Cite this

@article{21c82b42e667411980f2902c4c44ecd6,

title = "Phase equilibria in the ternary system methyl 1,1-dimethylethyl ether + oxolane + heptane",

abstract = "Vapor-liquid equilibrium at 94 kPa has been determined for the ternary system methyl 1,1-dimethylethyl ether (MTBE) + oxolane + heptane. The system deviates positively from ideality and no azeotrope is present The ternary activity coefficients and the boiling points of the system have been correlated with the composition using the Redlich-Kister, Wilson, NRTL, UNIQUAC, UNIFAC, and Wisniak-Tamir relations. Most of the models allow a good prediction of the activity coefficients of the ternary system from those of the pertinent binary systems.",

keywords = "Activity coefficients, Ternary systems, Vapor-liquid equilibrium",

author = "Jaime Wisniak and Gabriela Embon and Ran Shafir",

year = "1998",

month = jan,

day = "1",

doi = "10.1080/00319109808035919",

language = "English",

volume = "36",

pages = "37--51",

journal = "Physics and Chemistry of Liquids",

issn = "0031-9104",

publisher = "Taylor and Francis Ltd.",

number = "1",

}

TY - JOUR

T1 - Phase equilibria in the ternary system methyl 1,1-dimethylethyl ether + oxolane + heptane

AU - Wisniak, Jaime

AU - Embon, Gabriela

AU - Shafir, Ran

PY - 1998/1/1

Y1 - 1998/1/1

N2 - Vapor-liquid equilibrium at 94 kPa has been determined for the ternary system methyl 1,1-dimethylethyl ether (MTBE) + oxolane + heptane. The system deviates positively from ideality and no azeotrope is present The ternary activity coefficients and the boiling points of the system have been correlated with the composition using the Redlich-Kister, Wilson, NRTL, UNIQUAC, UNIFAC, and Wisniak-Tamir relations. Most of the models allow a good prediction of the activity coefficients of the ternary system from those of the pertinent binary systems.

AB - Vapor-liquid equilibrium at 94 kPa has been determined for the ternary system methyl 1,1-dimethylethyl ether (MTBE) + oxolane + heptane. The system deviates positively from ideality and no azeotrope is present The ternary activity coefficients and the boiling points of the system have been correlated with the composition using the Redlich-Kister, Wilson, NRTL, UNIQUAC, UNIFAC, and Wisniak-Tamir relations. Most of the models allow a good prediction of the activity coefficients of the ternary system from those of the pertinent binary systems.

KW - Activity coefficients

KW - Ternary systems

KW - Vapor-liquid equilibrium

UR - http://www.scopus.com/inward/record.url?scp=0031652541&partnerID=8YFLogxK

U2 - 10.1080/00319109808035919

DO - 10.1080/00319109808035919

M3 - Article

AN - SCOPUS:0031652541

SN - 0031-9104

VL - 36

SP - 37

EP - 51

JO - Physics and Chemistry of Liquids

JF - Physics and Chemistry of Liquids

IS - 1

ER -

Phase equilibria in the ternary system methyl 1,1-dimethylethyl ether + oxolane + heptane

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this