PHASE TRANSITIONS IN COPRECIPITATED NiO-WO//3 SYSTEM IN CALCINATION, REDUCTION, AND SULFIDING.

D. A. Agievskii, L. I. Pavlova, M. V. Landau, V. I. Kvashonkin, G. D. Chukin

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

X-ray diffraction and electron microscopy have been used in an investigation of the shaping of phase composition and structure of a coprecipitated NiO-WO//3 system in calcination, reduction, and sulfiding. It has been shown that calcination, when it leads to the formation of crystalline NiWO//4, lowers the efficiency of reduction and sulfiding to a considerable degree. A step-temperature sulfiding operation, in comparison with isothermal sulfiding, gives a less ordered structure of the WS//2, with loose packing of the particles into agglomerates.

Original languageEnglish
Pages (from-to)1042-1047
Number of pages6
JournalKinetics and Catalysis
Volume26
Issue number5 pt 2
StatePublished - 1 Sep 1985
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry (all)
  • Modeling and Simulation
  • Computer Science Applications

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