Phenyl-Modified Carbon Nitride Quantum Dots with Distinct Photoluminescence Behavior

A novel type of quantum dot (Ph-CN) is manufactured from graphitic carbon nitride by "lining" the carbon nitride structure with phenyl groups through supramolecular preorganization. This approach requires no chemical etching or hydrothermal treatments like other competing nanoparticle syntheses and is easy and safe to use. The Ph-CN nanoparticles exhibit bright, tunable fluorescence, with a high quantum yield of 48.4 % in aqueous colloidal suspensions. Interestingly, the observed Stokes shift of approximately 200nm is higher than the maximum values reported for carbon nitride based fluorophores. The high quantum yield and the large Stokes shift are related to the structural surface organization of the phenyl groups, which affects the π-electron delocalization in the conjugated carbon nitride networks and induces colloidal stability. The remarkable performance of the Ph-CN nanoparticles in imaging is demonstrated by a simple incubation study with HeLa cells. A fluorescence quantum yield of approximately 48 % and a large Stokes shift of 200nm were determined for phenyl-modified carbon nitride quantum dots, which were obtained through a supramolecular preorganization method. The remarkable emission properties are due to the structural surface organization of the phenyl groups, which alters the π-electron delocalization in the conjugated networks.