Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum

A. A. Pasynskii; Yu V. Torubaev; A. V. Pavlova; S. S. Shapovalov; I. V. Skabitskii; G. L. Denisov

doi:10.1134/S1070328414090061

Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum

A. A. Pasynskii, Yu V. Torubaev, A. V. Pavlova, S. S. Shapovalov, I. V. Skabitskii, G. L. Denisov

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A reaction of CpFe(CO)₂TePh with Re(CO)₃(THF) ₂Cl in THF gave the heterometallic complex [CpFe(CO) ₂(μ-TePh)]₂Re(CO)₃Cl (I). Either iron atom in complex I is linked to rhenium by only one Phenyltellurolate bridge. When treated with (Dppe)Pt(TePh)₂, complex I underwent transmetalation by elimination of two CpFe(CO)₂TePh molecules followed by the formation of the heterometallic chelate complex (Dppe)Pt(μ-TePh)₂Re(CO) ₃Cl (II). Complex II was also obtained in an independent way from (Dppe)Pt(TePh)₂ and Re(CO)₃(THF)₂. Structures I and II (II · MePh and II · CDCl₃) were identified by X-ray diffraction (CIF file, CCDC nos. 981467, 981468, and 981469, respectively).

Original language	English
Pages (from-to)	611-616
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	40
Issue number	9
DOIs	https://doi.org/10.1134/S1070328414090061
State	Published - 1 Jan 2014
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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Pasynskii, A. A., Torubaev, Y. V., Pavlova, A. V., Shapovalov, S. S., Skabitskii, I. V., & Denisov, G. L. (2014). Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 40(9), 611-616. https://doi.org/10.1134/S1070328414090061

@article{7712ecda3a1348d1ac1390f385ce6f60,

title = "Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum",

abstract = "A reaction of CpFe(CO)2TePh with Re(CO)3(THF) 2Cl in THF gave the heterometallic complex [CpFe(CO) 2(μ-TePh)]2Re(CO)3Cl (I). Either iron atom in complex I is linked to rhenium by only one Phenyltellurolate bridge. When treated with (Dppe)Pt(TePh)2, complex I underwent transmetalation by elimination of two CpFe(CO)2TePh molecules followed by the formation of the heterometallic chelate complex (Dppe)Pt(μ-TePh)2Re(CO) 3Cl (II). Complex II was also obtained in an independent way from (Dppe)Pt(TePh)2 and Re(CO)3(THF)2. Structures I and II (II · MePh and II · CDCl3) were identified by X-ray diffraction (CIF file, CCDC nos. 981467, 981468, and 981469, respectively).",

author = "Pasynskii, {A. A.} and Torubaev, {Yu V.} and Pavlova, {A. V.} and Shapovalov, {S. S.} and Skabitskii, {I. V.} and Denisov, {G. L.}",

note = "Funding Information: ACKNOWLEDGMENTS This work was supported by the Russian Founda tion for Basic Research (project nos. 12 03 00860, 12 03 33101), the Division of Chemistry and Materials Sciences of the Russian Academy of Sciences (grant OKh 1.3), the Presidium of the Russian Academy of Sciences (grant 8P23), and the Council on Grants at the President of the Russian Federation (MK 5635.2013.3, MK 7179.2012.3).",

year = "2014",

month = jan,

day = "1",

doi = "10.1134/S1070328414090061",

language = "English",

volume = "40",

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journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

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Pasynskii, AA, Torubaev, YV, Pavlova, AV, Shapovalov, SS, Skabitskii, IV & Denisov, GL 2014, 'Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 40, no. 9, pp. 611-616. https://doi.org/10.1134/S1070328414090061

Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum. / Pasynskii, A. A.; Torubaev, Yu V.; Pavlova, A. V. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 40, No. 9, 01.01.2014, p. 611-616.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Pavlova, A. V.

AU - Shapovalov, S. S.

AU - Skabitskii, I. V.

AU - Denisov, G. L.

N1 - Funding Information: ACKNOWLEDGMENTS This work was supported by the Russian Founda tion for Basic Research (project nos. 12 03 00860, 12 03 33101), the Division of Chemistry and Materials Sciences of the Russian Academy of Sciences (grant OKh 1.3), the Presidium of the Russian Academy of Sciences (grant 8P23), and the Council on Grants at the President of the Russian Federation (MK 5635.2013.3, MK 7179.2012.3).

PY - 2014/1/1

Y1 - 2014/1/1

N2 - A reaction of CpFe(CO)2TePh with Re(CO)3(THF) 2Cl in THF gave the heterometallic complex [CpFe(CO) 2(μ-TePh)]2Re(CO)3Cl (I). Either iron atom in complex I is linked to rhenium by only one Phenyltellurolate bridge. When treated with (Dppe)Pt(TePh)2, complex I underwent transmetalation by elimination of two CpFe(CO)2TePh molecules followed by the formation of the heterometallic chelate complex (Dppe)Pt(μ-TePh)2Re(CO) 3Cl (II). Complex II was also obtained in an independent way from (Dppe)Pt(TePh)2 and Re(CO)3(THF)2. Structures I and II (II · MePh and II · CDCl3) were identified by X-ray diffraction (CIF file, CCDC nos. 981467, 981468, and 981469, respectively).

AB - A reaction of CpFe(CO)2TePh with Re(CO)3(THF) 2Cl in THF gave the heterometallic complex [CpFe(CO) 2(μ-TePh)]2Re(CO)3Cl (I). Either iron atom in complex I is linked to rhenium by only one Phenyltellurolate bridge. When treated with (Dppe)Pt(TePh)2, complex I underwent transmetalation by elimination of two CpFe(CO)2TePh molecules followed by the formation of the heterometallic chelate complex (Dppe)Pt(μ-TePh)2Re(CO) 3Cl (II). Complex II was also obtained in an independent way from (Dppe)Pt(TePh)2 and Re(CO)3(THF)2. Structures I and II (II · MePh and II · CDCl3) were identified by X-ray diffraction (CIF file, CCDC nos. 981467, 981468, and 981469, respectively).

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U2 - 10.1134/S1070328414090061

DO - 10.1134/S1070328414090061

M3 - Article

AN - SCOPUS:84906890197

SN - 1070-3284

VL - 40

SP - 611

EP - 616

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 9

ER -

Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum

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