Photoactivation of ruthenium olefin metathesis initiators

Amos Ben-Asuly; Anna Aharoni; Charles E. Diesendruck; Yuval Vidavsky; Israel Goldberg; Bernd F. Straub; N. Gabriel Lemcoff

doi:10.1021/om9004302

Photoactivation of ruthenium olefin metathesis initiators

Amos Ben-Asuly
, Anna Aharoni
, Charles E. Diesendruck
, Yuval Vidavsky
, Israel Goldberg
, Bernd F. Straub
, N. Gabriel Lemcoff

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

119 Scopus citations

Abstract

UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro - trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature.

Original language	English
Pages (from-to)	4652-4655
Number of pages	4
Journal	Organometallics
Volume	28
Issue number	16
DOIs	https://doi.org/10.1021/om9004302
State	Published - 24 Aug 2009

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om9004302

Cite this

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title = "Photoactivation of ruthenium olefin metathesis initiators",

abstract = "UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro - trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature.",

author = "Amos Ben-Asuly and Anna Aharoni and Diesendruck, \{Charles E.\} and Yuval Vidavsky and Israel Goldberg and Straub, \{Bernd F.\} and Lemcoff, \{N. Gabriel\}",

year = "2009",

month = aug,

day = "24",

doi = "10.1021/om9004302",

language = "English",

volume = "28",

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journal = "Organometallics",

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T1 - Photoactivation of ruthenium olefin metathesis initiators

AU - Ben-Asuly, Amos

AU - Aharoni, Anna

AU - Diesendruck, Charles E.

AU - Vidavsky, Yuval

AU - Goldberg, Israel

AU - Straub, Bernd F.

AU - Lemcoff, N. Gabriel

PY - 2009/8/24

Y1 - 2009/8/24

N2 - UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro - trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature.

AB - UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro - trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature.

UR - https://www.scopus.com/pages/publications/68949178867

U2 - 10.1021/om9004302

DO - 10.1021/om9004302

M3 - Article

AN - SCOPUS:68949178867

SN - 0276-7333

VL - 28

SP - 4652

EP - 4655

JO - Organometallics

JF - Organometallics

IS - 16

ER -

Photoactivation of ruthenium olefin metathesis initiators

Abstract

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