Photoactivation of ruthenium phosphite complexes for olefin metathesis

Or Eivgi, Stefano Guidone, Alexander Frenklah, Sebastian Kozuch, Israel Goldberg, N. Gabriel Lemcoff

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The commercially available catalyst cis-Caz-1 is extremely robust, especially when reactions are performed in an atmosphere of air. This phosphite-containing ruthenium complex only shows olefin metathesis activity at high temperatures. Herein, we report photoactivation of cis-Caz-1 at room temperature with UVA light. Thus, a wide variety of olefin metathesis reactions was performed under mild conditions with good yields. In addition, we report the synthesis, characterization, and catalytic activity of a phosphite-chelated ruthenium benzylidene complex, cis-PhosRu-1, which can be efficiently activated either by irradiation with visible light (λ = 405 nm) or by heat.

Original languageEnglish
Pages (from-to)6413-6418
Number of pages6
JournalACS Catalysis
Volume8
Issue number7
DOIs
StatePublished - 6 Jul 2018

Keywords

  • latent catalysis
  • olefin metathesis
  • phosphates
  • photochemistry
  • ruthenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry (all)

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