Physical properties of oxygen-17 water. Absolute viscosity and density of H2 17O between 15 and 35°C

Albert I. Kudish; David Wolf; Fritz Steckel

doi:10.1039/F19747000484

Physical properties of oxygen-17 water. Absolute viscosity and density of H₂ ¹⁷O between 15 and 35°C

Albert I. Kudish
, David Wolf
, Fritz Steckel

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100% H ₂ ¹⁷O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53% ¹⁷O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H₂ ¹⁷O relative to natural water. The viscosity ratio at 25°C for H₂ ¹⁷O/H₂ ¹⁶O is 1.0226, whereas that for H ₂ ¹⁸O/H₂ ¹⁶O and D₂ ¹⁶O/H₂ ¹⁶O is 1.0536 and 1.2316, respectively.

Original language	English
Pages (from-to)	484-489
Number of pages	6
Journal	Journal of the Chemical Society, Faraday Transactions I
Volume	70
DOIs	https://doi.org/10.1039/F19747000484
State	Published - 1 Jan 1974
Externally published	Yes

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General Chemistry

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@article{dc29ac39984a422384dc65a837ddde41,

title = "Physical properties of oxygen-17 water. Absolute viscosity and density of H2 17O between 15 and 35°C",

abstract = "The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100\% H 2 17O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53\% 17O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H2 17O relative to natural water. The viscosity ratio at 25°C for H2 17O/H2 16O is 1.0226, whereas that for H 2 18O/H2 16O and D2 16O/H2 16O is 1.0536 and 1.2316, respectively.",

author = "Kudish, \{Albert I.\} and David Wolf and Fritz Steckel",

year = "1974",

month = jan,

day = "1",

doi = "10.1039/F19747000484",

language = "English",

volume = "70",

pages = "484--489",

journal = "Journal of the Chemical Society, Faraday Transactions I",

issn = "0300-9599",

publisher = "Faraday Division of the Chemical Society",

}

TY - JOUR

T1 - Physical properties of oxygen-17 water. Absolute viscosity and density of H2 17O between 15 and 35°C

AU - Kudish, Albert I.

AU - Wolf, David

AU - Steckel, Fritz

PY - 1974/1/1

Y1 - 1974/1/1

N2 - The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100% H 2 17O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53% 17O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H2 17O relative to natural water. The viscosity ratio at 25°C for H2 17O/H2 16O is 1.0226, whereas that for H 2 18O/H2 16O and D2 16O/H2 16O is 1.0536 and 1.2316, respectively.

AB - The absolute viscosity of four oxygen-17 water samples is reported at 5°C intervals between 15 and 35°C. The absolute viscosity of 100% H 2 17O is determined by extrapolation of the measured viscosity of a highly enriched oxygen-17 sample, i.e., 86.53% 17O. The values calculated, based upon Eyring's theory of viscosity, for the other oxygen-17 samples are in excellent agreement with the experimental results. The isotope effect has been analyzed for H2 17O relative to natural water. The viscosity ratio at 25°C for H2 17O/H2 16O is 1.0226, whereas that for H 2 18O/H2 16O and D2 16O/H2 16O is 1.0536 and 1.2316, respectively.

UR - https://www.scopus.com/pages/publications/0039858847

U2 - 10.1039/F19747000484

DO - 10.1039/F19747000484

M3 - Article

AN - SCOPUS:0039858847

SN - 0300-9599

VL - 70

SP - 484

EP - 489

JO - Journal of the Chemical Society, Faraday Transactions I

JF - Journal of the Chemical Society, Faraday Transactions I

ER -

Physical properties of oxygen-17 water. Absolute viscosity and density of H₂ ¹⁷O between 15 and 35°C

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