Picosecond kinetics by exchange broadening in the infrared and Raman. 3. CH3CN·IBr

Benyamin Cohen; Shmuel Weiss

doi:10.1021/j150662a021

Picosecond kinetics by exchange broadening in the infrared and Raman. 3. CH₃CN·IBr

Benyamin Cohen, Shmuel Weiss

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

Spectra of the v₂ and v₃ + v₄ bands of CH₃CN in the presence of IBr and in CCl₄ solution were measured over a range of temperatures. The spectra could be analyzed to reveal the kinetics of the CH₃CN + IBr ⇄ CH₃CN·IBr reaction, in the picosecond range. Association and dissociation rate constants were determined and, from them, activation energies and entropies.

Original language	English
Pages (from-to)	3974-3976
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	88
Issue number	18
DOIs	https://doi.org/10.1021/j150662a021
State	Published - 1 Jan 1984

ASJC Scopus subject areas

General Engineering
Physical and Theoretical Chemistry

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10.1021/j150662a021

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@article{9524f92f2f62491d8f53c28696fb322f,

title = "Picosecond kinetics by exchange broadening in the infrared and Raman. 3. CH3CN·IBr",

abstract = "Spectra of the v2 and v3 + v4 bands of CH3CN in the presence of IBr and in CCl4 solution were measured over a range of temperatures. The spectra could be analyzed to reveal the kinetics of the CH3CN + IBr ⇄ CH3CN·IBr reaction, in the picosecond range. Association and dissociation rate constants were determined and, from them, activation energies and entropies.",

author = "Benyamin Cohen and Shmuel Weiss",

year = "1984",

month = jan,

day = "1",

doi = "10.1021/j150662a021",

language = "English",

volume = "88",

pages = "3974--3976",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - Picosecond kinetics by exchange broadening in the infrared and Raman. 3. CH3CN·IBr

AU - Cohen, Benyamin

AU - Weiss, Shmuel

PY - 1984/1/1

Y1 - 1984/1/1

N2 - Spectra of the v2 and v3 + v4 bands of CH3CN in the presence of IBr and in CCl4 solution were measured over a range of temperatures. The spectra could be analyzed to reveal the kinetics of the CH3CN + IBr ⇄ CH3CN·IBr reaction, in the picosecond range. Association and dissociation rate constants were determined and, from them, activation energies and entropies.

AB - Spectra of the v2 and v3 + v4 bands of CH3CN in the presence of IBr and in CCl4 solution were measured over a range of temperatures. The spectra could be analyzed to reveal the kinetics of the CH3CN + IBr ⇄ CH3CN·IBr reaction, in the picosecond range. Association and dissociation rate constants were determined and, from them, activation energies and entropies.

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U2 - 10.1021/j150662a021

DO - 10.1021/j150662a021

M3 - Article

AN - SCOPUS:33845469648

SN - 0022-3654

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SP - 3974

EP - 3976

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 18

ER -

Picosecond kinetics by exchange broadening in the infrared and Raman. 3. CH₃CN·IBr

Abstract

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