Picosecond kinetics by exchange broadening in the infrared and Raman. 3. CH3CN·IBr

Benyamin Cohen, Shmuel Weiss

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Spectra of the v2 and v3 + v4 bands of CH3CN in the presence of IBr and in CCl4 solution were measured over a range of temperatures. The spectra could be analyzed to reveal the kinetics of the CH3CN + IBr ⇄ CH3CN·IBr reaction, in the picosecond range. Association and dissociation rate constants were determined and, from them, activation energies and entropies.

Original languageEnglish
Pages (from-to)3974-3976
Number of pages3
JournalJournal of Physical Chemistry
Volume88
Issue number18
DOIs
StatePublished - 1 Jan 1984

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