Polarization selection rules for the allowed optical transitions in europium-terbium double activated calcium tungstate phosphor

The paper is devoted to the problem of the optical anisotropy of the rare-earth ions occupying low-symmetry positions in crystals. The crystal field multiplets arising from LSJ terms of Eu³⁺ and Tb³⁺ ions in the crystal field of calcium tungstate scheelite (CaWO₄) are analyzed (S₄ point symmetry). The selection rules, in particular, polarization rules for the allowed electric dipole optical transitions in the electronic shells of the Eu³⁺ and Tb³⁺ in CaWO ₄ host lattice are discussed. Special attention is paid to the study of the angular (polarization) dependence of the two-photon absorption that seems to be an effective tool for the understanding of the complicated optical pattern. The peculiarities of the anisotropy of the two-photon absorption prove to be specific for each allowed dipole transition in S₄ symmetry center.