Poly[bis[2-(1-cyclohexenyl)ethyl-ammonium] di-μ-iodo-diodo-plumbate(II)]

David G. Billing; Andreas Lemmerer

doi:10.1107/S0108270106013953

Poly[bis[2-(1-cyclohexenyl)ethyl-ammonium] di-μ-iodo-diodo-plumbate(II)]

David G. Billing, Andreas Lemmerer

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The title compound, (C₈H₁₆N)₂[PbI ₄], crystallizes as an inorganic-organic hybrid perovskite, adopting the unusual 2a_p × 2a_p superstructure. As such, the structure consists of two-dimensional sheets of corner-sharing PbI₆ octahedra in the ab plane, separated by bilayers of 2-(1-cyclohexenyl) ethylammonium cations. The ethylammonium groups are not in the plane of the cyclohexenyl rings.

Original language	English
Pages (from-to)	m269-m271
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	62
Issue number	7
DOIs	https://doi.org/10.1107/S0108270106013953
State	Published - 1 Jul 2006
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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title = "Poly[bis[2-(1-cyclohexenyl)ethyl-ammonium] di-μ-iodo-diodo-plumbate(II)]",

abstract = "The title compound, (C8H16N)2[PbI 4], crystallizes as an inorganic-organic hybrid perovskite, adopting the unusual 2ap × 2ap superstructure. As such, the structure consists of two-dimensional sheets of corner-sharing PbI6 octahedra in the ab plane, separated by bilayers of 2-(1-cyclohexenyl) ethylammonium cations. The ethylammonium groups are not in the plane of the cyclohexenyl rings.",

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AU - Lemmerer, Andreas

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Y1 - 2006/7/1

N2 - The title compound, (C8H16N)2[PbI 4], crystallizes as an inorganic-organic hybrid perovskite, adopting the unusual 2ap × 2ap superstructure. As such, the structure consists of two-dimensional sheets of corner-sharing PbI6 octahedra in the ab plane, separated by bilayers of 2-(1-cyclohexenyl) ethylammonium cations. The ethylammonium groups are not in the plane of the cyclohexenyl rings.

AB - The title compound, (C8H16N)2[PbI 4], crystallizes as an inorganic-organic hybrid perovskite, adopting the unusual 2ap × 2ap superstructure. As such, the structure consists of two-dimensional sheets of corner-sharing PbI6 octahedra in the ab plane, separated by bilayers of 2-(1-cyclohexenyl) ethylammonium cations. The ethylammonium groups are not in the plane of the cyclohexenyl rings.

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Poly[bis[2-(1-cyclohexenyl)ethyl-ammonium] di-μ-iodo-diodo-plumbate(II)]

Abstract

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