Polycyclooctadiene complexes of rhodium(I): Direct access to organometallic nanoparticles

Sudheendran Mavila; Charles E. Diesendruck; Sivan Linde; Liron Amir; Rafi Shikler; N. Gabriel Lemcoff

doi:10.1002/anie.201300362

Polycyclooctadiene complexes of rhodium(I): Direct access to organometallic nanoparticles

Sudheendran Mavila, Charles E. Diesendruck, Sivan Linde, Liron Amir, Rafi Shikler, N. Gabriel Lemcoff

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [{RhCl(C₂H₄)₂}₂] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.

Original language	English
Pages (from-to)	5767-5770
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	22
DOIs	https://doi.org/10.1002/anie.201300362
State	Published - 27 May 2013

Keywords

alkene ligands
macromolecular hybrids
organometallic nanoparticles
polymers
rhodium

ASJC Scopus subject areas

Catalysis
Chemistry (all)

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10.1002/anie.201300362

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abstract = "Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [{RhCl(C2H4)2}2] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.",

keywords = "alkene ligands, macromolecular hybrids, organometallic nanoparticles, polymers, rhodium",

author = "Sudheendran Mavila and Diesendruck, {Charles E.} and Sivan Linde and Liron Amir and Rafi Shikler and Lemcoff, {N. Gabriel}",

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AU - Linde, Sivan

AU - Amir, Liron

AU - Shikler, Rafi

AU - Lemcoff, N. Gabriel

PY - 2013/5/27

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AB - Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [{RhCl(C2H4)2}2] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.

KW - alkene ligands

KW - macromolecular hybrids

KW - organometallic nanoparticles

KW - polymers

KW - rhodium

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Polycyclooctadiene complexes of rhodium(I): Direct access to organometallic nanoparticles

Abstract

Keywords

ASJC Scopus subject areas

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