Porous Graphene Oxide-Metal Ion Composite for Selective Sensing of Organophosphate Gases

Nitzan Shauloff, Nagappa L. Teradal, Raz Jelinek

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Organophosphates are used as agricultural pesticides and also encountered as toxic nerve agents in chemical warfare. Accordingly, development of sensors for detecting and monitoring organophosphate vapors is highly sought after. We present a new capacitive gas sensor exhibiting remarkable specificity and sensitivity toward the organophosphate nerve gas simulants triethyl-phosphate (TEP) and dimethyl methyl phosphate and the pesticide dichlorvos. Specifically, the capacitive sensor comprises a composite porous graphene oxide matrix intercalating cobalt or nickel ions, prepared through a simple freeze-drying procedure. We demonstrate that the porous graphene oxide/metal ion electrode undergoes fast capacitance changes only upon exposure to organophosphate vapors. Moreover, the sensor exhibits extraordinary sensitivity upon interactions with TEP. Detailed mechanistic analyses, carried out in comparison to porous graphene oxide coupled to other transition metal ions, reveal that the remarkable sensing properties of the Co2+ or Ni2+/porous graphene oxide systems likely arise from the distinct mode of metal ion incorporation into the graphene oxide host matrix and substitution of metal-complexed water ligands with organophosphate molecules. The new metal ion/porous graphene oxide capacitive sensor may be employed for alerting and monitoring organophosphate gases in different environments.

Original languageEnglish
Pages (from-to)1573-1581
Number of pages9
JournalACS Sensors
Volume5
Issue number6
DOIs
StatePublished - 26 Jun 2020

Keywords

  • capacitive vapor sensors
  • cobalt complexes
  • dielectric constant
  • organophosphates
  • porous graphene oxide
  • transition metal ions

ASJC Scopus subject areas

  • Bioengineering
  • Instrumentation
  • Process Chemistry and Technology
  • Fluid Flow and Transfer Processes

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