Abstract
Preferential excitation of the 3P°1 state of the lead atom and enhanced emission in the Pb(3P °1Pb(3P°1→ 1D2) transition at 722.9 nm have been observed following the detonation of lead azide, Pb(N3)2. The detonation is initiated by a short laser pulse and the products are expanded through a supersonic nozzle. It is suggested that the enhanced emission is due to preferential excitation of Pb(3P°1) via energy transfer from electronically excited N2 combined with the effect of self-trapping of the emission from 3P° 1 to the 3P0,1,2 states. The implications to short-wavelength chemical lasers are discussed.
Original language | English |
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Pages (from-to) | 322-324 |
Number of pages | 3 |
Journal | Applied Physics Letters |
Volume | 58 |
Issue number | 4 |
DOIs | |
State | Published - 1 Dec 1991 |
ASJC Scopus subject areas
- Physics and Astronomy (miscellaneous)