Preparation, characterization and thermal degradation studies of bi-functional cation-exchange membranes

Amit K. Thakur; Ravi P. Pandey; Vinod K. Shahi

doi:10.1016/j.desal.2015.03.037

Preparation, characterization and thermal degradation studies of bi-functional cation-exchange membranes

Amit K. Thakur, Ravi P. Pandey, Vinod K. Shahi

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Cross-linked divinylbenzene (DVB) based bi-functional copolymer (BFC) was synthesized using acrylic acid and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) by free radical copolymerisation reaction. Simple solution casting technique was used to fabricate the bi-functional cation-exchange membranes using polyvinyl alcohol (PVA) as plasticizer. To deliberate the structural and morphological analyses and asses the density of functional groups, state of water, and conductivity of developed membranes, physicochemical characterizations were carried out. Well optimized PVA/BFC-70 membrane showed high bound water content (3.60%) with high membrane conductivity (3.67×10^-2Scm^-1) and ion-exchange capacity (1.30mequivg^-1). The reported CEM, especially PVA/BFC-70, was assessed for the electrochemical applications.

Original language	English
Pages (from-to)	206-215
Number of pages	10
Journal	Desalination
Volume	367
DOIs	https://doi.org/10.1016/j.desal.2015.03.037
State	Published - 1 Jul 2015
Externally published	Yes

Keywords

Cation exchange membrane
Counter-ion transport number
Electrodialysis
Membrane conductivity
Permselectivity

ASJC Scopus subject areas

Chemistry (all)
Chemical Engineering (all)
Materials Science (all)
Water Science and Technology
Mechanical Engineering

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10.1016/j.desal.2015.03.037

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title = "Preparation, characterization and thermal degradation studies of bi-functional cation-exchange membranes",

abstract = "Cross-linked divinylbenzene (DVB) based bi-functional copolymer (BFC) was synthesized using acrylic acid and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) by free radical copolymerisation reaction. Simple solution casting technique was used to fabricate the bi-functional cation-exchange membranes using polyvinyl alcohol (PVA) as plasticizer. To deliberate the structural and morphological analyses and asses the density of functional groups, state of water, and conductivity of developed membranes, physicochemical characterizations were carried out. Well optimized PVA/BFC-70 membrane showed high bound water content (3.60%) with high membrane conductivity (3.67×10-2Scm-1) and ion-exchange capacity (1.30mequivg-1). The reported CEM, especially PVA/BFC-70, was assessed for the electrochemical applications.",

keywords = "Cation exchange membrane, Counter-ion transport number, Electrodialysis, Membrane conductivity, Permselectivity",

author = "Thakur, {Amit K.} and Pandey, {Ravi P.} and Shahi, {Vinod K.}",

note = "Funding Information: This work is supported by Department of Science and Technology, New Delhi (Project no. SR/S1/PC-62/2012 ), Govt. of India. Instrumental support received from Analytical Science Division, CSMCRI is also gratefully acknowledged. Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2015",

month = jul,

day = "1",

doi = "10.1016/j.desal.2015.03.037",

language = "English",

volume = "367",

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journal = "Desalination",

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T1 - Preparation, characterization and thermal degradation studies of bi-functional cation-exchange membranes

AU - Thakur, Amit K.

AU - Pandey, Ravi P.

AU - Shahi, Vinod K.

N1 - Funding Information: This work is supported by Department of Science and Technology, New Delhi (Project no. SR/S1/PC-62/2012 ), Govt. of India. Instrumental support received from Analytical Science Division, CSMCRI is also gratefully acknowledged. Publisher Copyright: © 2015 Elsevier B.V.

PY - 2015/7/1

Y1 - 2015/7/1

N2 - Cross-linked divinylbenzene (DVB) based bi-functional copolymer (BFC) was synthesized using acrylic acid and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) by free radical copolymerisation reaction. Simple solution casting technique was used to fabricate the bi-functional cation-exchange membranes using polyvinyl alcohol (PVA) as plasticizer. To deliberate the structural and morphological analyses and asses the density of functional groups, state of water, and conductivity of developed membranes, physicochemical characterizations were carried out. Well optimized PVA/BFC-70 membrane showed high bound water content (3.60%) with high membrane conductivity (3.67×10-2Scm-1) and ion-exchange capacity (1.30mequivg-1). The reported CEM, especially PVA/BFC-70, was assessed for the electrochemical applications.

AB - Cross-linked divinylbenzene (DVB) based bi-functional copolymer (BFC) was synthesized using acrylic acid and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) by free radical copolymerisation reaction. Simple solution casting technique was used to fabricate the bi-functional cation-exchange membranes using polyvinyl alcohol (PVA) as plasticizer. To deliberate the structural and morphological analyses and asses the density of functional groups, state of water, and conductivity of developed membranes, physicochemical characterizations were carried out. Well optimized PVA/BFC-70 membrane showed high bound water content (3.60%) with high membrane conductivity (3.67×10-2Scm-1) and ion-exchange capacity (1.30mequivg-1). The reported CEM, especially PVA/BFC-70, was assessed for the electrochemical applications.

KW - Cation exchange membrane

KW - Counter-ion transport number

KW - Electrodialysis

KW - Membrane conductivity

KW - Permselectivity

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U2 - 10.1016/j.desal.2015.03.037

DO - 10.1016/j.desal.2015.03.037

M3 - Article

AN - SCOPUS:84927932915

SN - 0011-9164

VL - 367

SP - 206

EP - 215

JO - Desalination

JF - Desalination

ER -

Preparation, characterization and thermal degradation studies of bi-functional cation-exchange membranes

Abstract

Keywords

ASJC Scopus subject areas

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