Pressure-induced amorphization of A-site-deficient double perovskite Ln1/3MO3 (Ln = Pr, Nd, M = Nb, Ta)

O. Noked, A. Melchior, R. Shuker, R. Steininger, B. J. Kennedy, E. Sterer

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

High-pressure X-ray diffraction measurements have demonstrated that the cation-deficient perovskites Pr1/3NbO3, Pr1/3TaO3, Nd1/3NbO3, and Nd1/3TaO3 undergo irreversible pressure-induced amorphization (PIA). This occurs near 14.5 GPa for the niobates and 18.5 GPa for the tantalates. The unit cell volumes of the four oxides show an almost linear decrease as the pressure is increased. It is concluded that the PIA transition occurs at higher pressures in the tantalates due to the lower MO6 initial tilting at ambient conditions, which is associated with the larger atomic mass of the tantalum. The behavior of these oxides is compared to that of CaTiO3, and the role of both the weakening of the M-O-M π-bonding and the cation vacancies on the observed structural changes is discussed.

Original languageEnglish
Pages (from-to)439-447
Number of pages9
JournalPhysics and Chemistry of Minerals
Volume41
Issue number6
DOIs
StatePublished - 1 Jan 2014

Keywords

  • High pressure
  • Perovskite
  • Pressure-induced amorphization

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