The oxidation of (1,4,7,10,13-penta-azacyclohexadecane)nickel(II) by OH· radicals in aqueous solutions was studied, and the properties of the resulting nickel(III) complex are compared with those of analogous complexes [NiL]3+ where L is a tetra-azacyclotetradecane ligand. The difference in the properties is attributed to the fifth nitrogen donor atom which decreases the acidity of the central tervalent nickel.
|Number of pages||2|
|Journal||Journal of the Chemical Society. Dalton Transactions|
|State||Published - 1 Jan 1983|
ASJC Scopus subject areas
- Chemistry (all)