Properties of Copper(II) Hydride Formed in the Reaction of Aquacopper(I) Ions with Hydrogen Atoms. A Pulse Radiolytic Study

W. A. Mulac; Dan Meyerstein

doi:10.1021/ic00135a017

Properties of Copper(II) Hydride Formed in the Reaction of Aquacopper(I) Ions with Hydrogen Atoms. A Pulse Radiolytic Study

W. A. Mulac, Dan Meyerstein

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21 Scopus citations

Abstract

The spectrum of Cu-H⁺(aq), formed via Cu⁺ + H → Cu-H⁺(aq) in aqueous solutions, is reported. In neutral solutions it decomposes via Cu-H⁺(aq) + H₂O → Cu²⁺(aq) + H₂ + OH⁻(aq) with a rate of 4 × 10³ s⁻¹. The properties of Cu-H⁺(aq) are discussed and compared with those of similar Cu^II-R compounds.

Original language	English
Pages (from-to)	1782-1784
Number of pages	3
Journal	Inorganic Chemistry
Volume	21
Issue number	5
DOIs	https://doi.org/10.1021/ic00135a017
State	Published - 1 Jan 1982
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00135a017

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title = "Properties of Copper(II) Hydride Formed in the Reaction of Aquacopper(I) Ions with Hydrogen Atoms. A Pulse Radiolytic Study",

abstract = "The spectrum of Cu-H+(aq), formed via Cu+ + H → Cu-H+(aq) in aqueous solutions, is reported. In neutral solutions it decomposes via Cu-H+(aq) + H2O → Cu2+(aq) + H2 + OH−(aq) with a rate of 4 × 103 s−1. The properties of Cu-H+(aq) are discussed and compared with those of similar CuII-R compounds.",

author = "Mulac, {W. A.} and Dan Meyerstein",

year = "1982",

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journal = "Inorganic Chemistry",

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T1 - Properties of Copper(II) Hydride Formed in the Reaction of Aquacopper(I) Ions with Hydrogen Atoms. A Pulse Radiolytic Study

AU - Mulac, W. A.

AU - Meyerstein, Dan

PY - 1982/1/1

Y1 - 1982/1/1

N2 - The spectrum of Cu-H+(aq), formed via Cu+ + H → Cu-H+(aq) in aqueous solutions, is reported. In neutral solutions it decomposes via Cu-H+(aq) + H2O → Cu2+(aq) + H2 + OH−(aq) with a rate of 4 × 103 s−1. The properties of Cu-H+(aq) are discussed and compared with those of similar CuII-R compounds.

AB - The spectrum of Cu-H+(aq), formed via Cu+ + H → Cu-H+(aq) in aqueous solutions, is reported. In neutral solutions it decomposes via Cu-H+(aq) + H2O → Cu2+(aq) + H2 + OH−(aq) with a rate of 4 × 103 s−1. The properties of Cu-H+(aq) are discussed and compared with those of similar CuII-R compounds.

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U2 - 10.1021/ic00135a017

DO - 10.1021/ic00135a017

M3 - Article

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SN - 0020-1669

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SP - 1782

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JO - Inorganic Chemistry

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IS - 5

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Properties of Copper(II) Hydride Formed in the Reaction of Aquacopper(I) Ions with Hydrogen Atoms. A Pulse Radiolytic Study

Abstract

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