Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d3 Impurity in Crystals. Luminescence of CdIn2S4:Cr3+

L. L. Kulyuk, S. M. Popov, S. M. Ostrovsky, A. V. Palii, B. S. Tsukerblat

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A new model for the vibronic problem of luminescence of 3d3 impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo Jahn-Teller vibronic problem for the excited states. Spin-orbit splitting of 4T2 term and its mixing with 2E as well as the vibronic interaction with the full-symmetric (A1g) local mode is taken into account resulting in the [formula omitted] vibronic problem and [formula omitted], adiabatic problems. The band shape of the luminescence and the temperature dependence of the life-time decay emission are evaluated for Cr3+ ions in CdIn2S4:Cr single crystals. The proposed model provides a very good explanation of the experimental data.

Original languageEnglish
Pages (from-to)319-328
Number of pages10
JournalZeitschrift fur Physikalische Chemie
Issue number1
StatePublished - 1 Jan 1996
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry


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