Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d3 Impurity in Crystals. Luminescence of CdIn2S4:Cr3+

L. L. Kulyuk; S. M. Popov; S. M. Ostrovsky; A. V. Palii; B. S. Tsukerblat

doi:10.1524/zpch.1996.1.1.319

Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d³ Impurity in Crystals. Luminescence of CdIn₂S₄:Cr³⁺

L. L. Kulyuk, S. M. Popov, S. M. Ostrovsky, A. V. Palii, B. S. Tsukerblat

Research output: Contribution to journal › Article › peer-review

Abstract

A new model for the vibronic problem of luminescence of 3d³ impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo Jahn-Teller vibronic problem for the excited states. Spin-orbit splitting of ⁴T₂ term and its mixing with ²E as well as the vibronic interaction with the full-symmetric (A_1g) local mode is taken into account resulting in the [formula omitted] vibronic problem and [formula omitted], adiabatic problems. The band shape of the luminescence and the temperature dependence of the life-time decay emission are evaluated for Cr³⁺ ions in CdIn₂S₄:Cr single crystals. The proposed model provides a very good explanation of the experimental data.

Original language	English
Pages (from-to)	319-328
Number of pages	10
Journal	Zeitschrift fur Physikalische Chemie
Volume	1
Issue number	1
DOIs	https://doi.org/10.1524/zpch.1996.1.1.319
State	Published - 1 Jan 1996
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry

Access to Document

10.1524/zpch.1996.1.1.319

Cite this

@article{044bbbe33b4a420abf794097bfd7426a,

title = "Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d3 Impurity in Crystals. Luminescence of CdIn2S4:Cr3+",

abstract = "A new model for the vibronic problem of luminescence of 3d3 impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo Jahn-Teller vibronic problem for the excited states. Spin-orbit splitting of 4T2 term and its mixing with 2E as well as the vibronic interaction with the full-symmetric (A1g) local mode is taken into account resulting in the [formula omitted] vibronic problem and [formula omitted], adiabatic problems. The band shape of the luminescence and the temperature dependence of the life-time decay emission are evaluated for Cr3+ ions in CdIn2S4:Cr single crystals. The proposed model provides a very good explanation of the experimental data.",

author = "Kulyuk, {L. L.} and Popov, {S. M.} and Ostrovsky, {S. M.} and Palii, {A. V.} and Tsukerblat, {B. S.}",

year = "1996",

month = jan,

day = "1",

doi = "10.1524/zpch.1996.1.1.319",

language = "English",

volume = "1",

pages = "319--328",

journal = "Zeitschrift fur Physikalische Chemie",

issn = "0942-9352",

publisher = "Walter de Gruyter GmbH",

number = "1",

}

TY - JOUR

T1 - Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d3 Impurity in Crystals. Luminescence of CdIn2S4:Cr3+

AU - Kulyuk, L. L.

AU - Popov, S. M.

AU - Ostrovsky, S. M.

AU - Palii, A. V.

AU - Tsukerblat, B. S.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - A new model for the vibronic problem of luminescence of 3d3 impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo Jahn-Teller vibronic problem for the excited states. Spin-orbit splitting of 4T2 term and its mixing with 2E as well as the vibronic interaction with the full-symmetric (A1g) local mode is taken into account resulting in the [formula omitted] vibronic problem and [formula omitted], adiabatic problems. The band shape of the luminescence and the temperature dependence of the life-time decay emission are evaluated for Cr3+ ions in CdIn2S4:Cr single crystals. The proposed model provides a very good explanation of the experimental data.

AB - A new model for the vibronic problem of luminescence of 3d3 impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo Jahn-Teller vibronic problem for the excited states. Spin-orbit splitting of 4T2 term and its mixing with 2E as well as the vibronic interaction with the full-symmetric (A1g) local mode is taken into account resulting in the [formula omitted] vibronic problem and [formula omitted], adiabatic problems. The band shape of the luminescence and the temperature dependence of the life-time decay emission are evaluated for Cr3+ ions in CdIn2S4:Cr single crystals. The proposed model provides a very good explanation of the experimental data.

UR - http://www.scopus.com/inward/record.url?scp=85026055600&partnerID=8YFLogxK

U2 - 10.1524/zpch.1996.1.1.319

DO - 10.1524/zpch.1996.1.1.319

M3 - Article

AN - SCOPUS:85026055600

VL - 1

SP - 319

EP - 328

JO - Zeitschrift fur Physikalische Chemie

JF - Zeitschrift fur Physikalische Chemie

SN - 0942-9352

IS - 1

ER -

Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d³ Impurity in Crystals. Luminescence of CdIn₂S₄:Cr³⁺

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this