Pseudo-Jahn-Teller Vibronic Model of a Cubic 3d3 Impurity in Crystals. Luminescence of CdIn2S4:Cr3+

L. L. Kulyuk, S. M. Popov, B. S. Tsukerblat, S. M. Ostrovsky, A. V. Palii

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1 Scopus citations


A new model for the vibronic problem of luminescence of 3d3 impurity ions in the cubic environment is proposed. The approach developed is based on the numerical quantum-mechanical solution of the dynamic pseudo Jahn-Teller vibronic problem for the excited states. Spin-orbit splitting of 4t2 term and its mixing with 2E as well as the vibronic interaction with the full-symmetric local mode is taken into account resulting in the, vibronic problem and adiabatic problems. The band shape of the luminescence and the temperature dependence of the life-time decay emission are evaluated for Cr3+ ions in CdIn2S4:Cr single crystals. The proposed model provides a very good explanation of the experimental data.

Original languageEnglish
Pages (from-to)45-54
Number of pages10
JournalZeitschrift fur Physikalische Chemie
StatePublished - 1 Jan 1997
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry


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