Pulse radiolytic studies of the competition H + H and H + ferricyanide. The absolute rate constants

J. Rabani, D. Meyerstein

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

The bimolecular rate constant of the reaction of hydrogen atoms with ferricyanide ions has been measured in aqueous solutions. We get k(H + Fe(CN)63-) = (6.5 ± 0.5) × 109 M-1 sec-1 in the region pH 2-3. Competition between H + Fe(CN)63- and H + H yielded 2k(H + H) = (2.5 ± 0.4) × 1010 M-1 sec-1.

Original languageEnglish
Pages (from-to)1599-1603
Number of pages5
JournalJournal of Physical Chemistry
Volume72
Issue number5
DOIs
StatePublished - 1 Jan 1968
Externally publishedYes

ASJC Scopus subject areas

  • Engineering (all)
  • Physical and Theoretical Chemistry

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