Pyrroles from ketoximes and acetylene. 45. A new route to 2,2-dipyrroles

S. E. Korostova; S. G. Shevchenko; M. V. Sigalov; N. I. Golovanova

doi:10.1007/BF00480830

Pyrroles from ketoximes and acetylene. 45. A new route to 2,2-dipyrroles

S. E. Korostova, S. G. Shevchenko, M. V. Sigalov, N. I. Golovanova

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Abstract

The reaction of 1-methyl-2-acetylpyrrole oxime with acetylene at atmospheric and increased pressure can be catalyzed by KOH-DMSO superbase to give 1-methyl-2-(2-pyrrolyl)pyrrole, N-vinyl-2-[1-methyl(2-pyrrolyl)]pyrrole, and the reaction intermediate methyl-2-(1-methylpyrrolyl)-O-vinyloxime.

Original language	English
Pages (from-to)	363-365
Number of pages	3
Journal	Chemistry of Heterocyclic Compounds
Volume	27
Issue number	4
DOIs	https://doi.org/10.1007/BF00480830
State	Published - 1 Apr 1991
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Pyrroles from ketoximes and acetylene. 45. A new route to 2,2-dipyrroles",

abstract = "The reaction of 1-methyl-2-acetylpyrrole oxime with acetylene at atmospheric and increased pressure can be catalyzed by KOH-DMSO superbase to give 1-methyl-2-(2-pyrrolyl)pyrrole, N-vinyl-2-[1-methyl(2-pyrrolyl)]pyrrole, and the reaction intermediate methyl-2-(1-methylpyrrolyl)-O-vinyloxime.",

author = "Korostova, {S. E.} and Shevchenko, {S. G.} and Sigalov, {M. V.} and Golovanova, {N. I.}",

year = "1991",

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T1 - Pyrroles from ketoximes and acetylene. 45. A new route to 2,2-dipyrroles

AU - Korostova, S. E.

AU - Shevchenko, S. G.

AU - Sigalov, M. V.

AU - Golovanova, N. I.

PY - 1991/4/1

Y1 - 1991/4/1

N2 - The reaction of 1-methyl-2-acetylpyrrole oxime with acetylene at atmospheric and increased pressure can be catalyzed by KOH-DMSO superbase to give 1-methyl-2-(2-pyrrolyl)pyrrole, N-vinyl-2-[1-methyl(2-pyrrolyl)]pyrrole, and the reaction intermediate methyl-2-(1-methylpyrrolyl)-O-vinyloxime.

AB - The reaction of 1-methyl-2-acetylpyrrole oxime with acetylene at atmospheric and increased pressure can be catalyzed by KOH-DMSO superbase to give 1-methyl-2-(2-pyrrolyl)pyrrole, N-vinyl-2-[1-methyl(2-pyrrolyl)]pyrrole, and the reaction intermediate methyl-2-(1-methylpyrrolyl)-O-vinyloxime.

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U2 - 10.1007/BF00480830

DO - 10.1007/BF00480830

M3 - Article

AN - SCOPUS:34249927551

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JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

IS - 4

ER -

Pyrroles from ketoximes and acetylene. 45. A new route to 2,2-dipyrroles

Abstract

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