Quantification of surface Li in 16.4% CuLi alloys by direct recoil and Auger analysis of element specific chemisorption complexes

H. K. Schmidt; L. R. Anderson; J. A. Schultz; A. Krauss; B. Biwer; D. M. Gruen; N. Shamir; M. Mintz

doi:10.1116/1.575606

Quantification of surface Li in 16.4% CuLi alloys by direct recoil and Auger analysis of element specific chemisorption complexes

H. K. Schmidt, L. R. Anderson, J. A. Schultz, A. Krauss, B. Biwer, D. M. Gruen, N. Shamir, M. Mintz

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2 Scopus citations

Abstract

Methoxyl carbon and oxygen are shown to specifically add to the lithium fraction of a CuLi surface exposed to methanol. The lithium surface fraction is determined by direct recoil spectroscopic (DRS) measurement of the H, C, and O added to the surface by methanol exposure and by subsequent comparison to the amounts of C, O, and metal determined by Auger electron spectroscopy (AES) or x-ray photoelectron spectroscopy (XPS). Direct determination of surface Li by AES or XPS is complicated by relatively large sampling depths (5 or 20 A). The indirect determination of surface Li by methanol chemisorption/AES has been used to calibrate the sensitivity of 5-keV K⁺DRS for lithium.

Original language	English
Pages (from-to)	2073-2076
Number of pages	4
Journal	Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
Volume	6
Issue number	3
DOIs	https://doi.org/10.1116/1.575606
State	Published - 1 Jan 1988
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films

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Schmidt, H. K., Anderson, L. R., Schultz, J. A., Krauss, A., Biwer, B., Gruen, D. M., Shamir, N., & Mintz, M. (1988). Quantification of surface Li in 16.4% CuLi alloys by direct recoil and Auger analysis of element specific chemisorption complexes. Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, 6(3), 2073-2076. https://doi.org/10.1116/1.575606

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title = "Quantification of surface Li in 16.4% CuLi alloys by direct recoil and Auger analysis of element specific chemisorption complexes",

abstract = "Methoxyl carbon and oxygen are shown to specifically add to the lithium fraction of a CuLi surface exposed to methanol. The lithium surface fraction is determined by direct recoil spectroscopic (DRS) measurement of the H, C, and O added to the surface by methanol exposure and by subsequent comparison to the amounts of C, O, and metal determined by Auger electron spectroscopy (AES) or x-ray photoelectron spectroscopy (XPS). Direct determination of surface Li by AES or XPS is complicated by relatively large sampling depths (5 or 20 A). The indirect determination of surface Li by methanol chemisorption/AES has been used to calibrate the sensitivity of 5-keV K+DRS for lithium.",

author = "Schmidt, {H. K.} and Anderson, {L. R.} and Schultz, {J. A.} and A. Krauss and B. Biwer and Gruen, {D. M.} and N. Shamir and M. Mintz",

year = "1988",

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day = "1",

doi = "10.1116/1.575606",

language = "English",

volume = "6",

pages = "2073--2076",

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Quantification of surface Li in 16.4% CuLi alloys by direct recoil and Auger analysis of element specific chemisorption complexes. / Schmidt, H. K.; Anderson, L. R.; Schultz, J. A. et al.
In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, Vol. 6, No. 3, 01.01.1988, p. 2073-2076.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Quantification of surface Li in 16.4% CuLi alloys by direct recoil and Auger analysis of element specific chemisorption complexes

AU - Schmidt, H. K.

AU - Anderson, L. R.

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AU - Krauss, A.

AU - Biwer, B.

AU - Gruen, D. M.

AU - Shamir, N.

AU - Mintz, M.

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N2 - Methoxyl carbon and oxygen are shown to specifically add to the lithium fraction of a CuLi surface exposed to methanol. The lithium surface fraction is determined by direct recoil spectroscopic (DRS) measurement of the H, C, and O added to the surface by methanol exposure and by subsequent comparison to the amounts of C, O, and metal determined by Auger electron spectroscopy (AES) or x-ray photoelectron spectroscopy (XPS). Direct determination of surface Li by AES or XPS is complicated by relatively large sampling depths (5 or 20 A). The indirect determination of surface Li by methanol chemisorption/AES has been used to calibrate the sensitivity of 5-keV K+DRS for lithium.

AB - Methoxyl carbon and oxygen are shown to specifically add to the lithium fraction of a CuLi surface exposed to methanol. The lithium surface fraction is determined by direct recoil spectroscopic (DRS) measurement of the H, C, and O added to the surface by methanol exposure and by subsequent comparison to the amounts of C, O, and metal determined by Auger electron spectroscopy (AES) or x-ray photoelectron spectroscopy (XPS). Direct determination of surface Li by AES or XPS is complicated by relatively large sampling depths (5 or 20 A). The indirect determination of surface Li by methanol chemisorption/AES has been used to calibrate the sensitivity of 5-keV K+DRS for lithium.

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ER -

Quantification of surface Li in 16.4% CuLi alloys by direct recoil and Auger analysis of element specific chemisorption complexes

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