Reaction of α-alkoxyacroleins with semicarbazide and its S-, Se-, and NH-analogs

N. A. Keiko; T. N. Mamashvili; G. V. Rassolova; T. V. Kashik; I. D. Kalikhman; M. G. Vbronkov

doi:10.1007/BF00995696

Reaction of α-alkoxyacroleins with semicarbazide and its S-, Se-, and NH-analogs

N. A. Keiko, T. N. Mamashvili, G. V. Rassolova, T. V. Kashik, I. D. Kalikhman, M. G. Vbronkov

Research output: Contribution to journal › Article › peer-review

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Abstract

1. The reaction of α-alkoxyacroleins with semi-, thiosemi-, and selenosemicarbazides in a basic medium leads to the formation of semi-, thiosemi-, and selenosemicarbazones of α-alkoxyacrolein. The reactions of α-ethoxyacroleins with twofold excess amounts of semi- and selenosemicarbazides in acid media lead to disemi- and diselenosemicarbazones of methylglyoxal. 2. Determination of basicity constants of semicarbazide and its S-, Se-, and NH-analogs was carried out in acetonitrile.

Original language	English
Pages (from-to)	561-564
Number of pages	4
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	33
Issue number	3
DOIs	https://doi.org/10.1007/BF00995696
State	Published - 1 Jan 1984
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Reaction of α-alkoxyacroleins with semicarbazide and its S-, Se-, and NH-analogs",

abstract = "1. The reaction of α-alkoxyacroleins with semi-, thiosemi-, and selenosemicarbazides in a basic medium leads to the formation of semi-, thiosemi-, and selenosemicarbazones of α-alkoxyacrolein. The reactions of α-ethoxyacroleins with twofold excess amounts of semi- and selenosemicarbazides in acid media lead to disemi- and diselenosemicarbazones of methylglyoxal. 2. Determination of basicity constants of semicarbazide and its S-, Se-, and NH-analogs was carried out in acetonitrile.",

author = "Keiko, {N. A.} and Mamashvili, {T. N.} and Rassolova, {G. V.} and Kashik, {T. V.} and Kalikhman, {I. D.} and Vbronkov, {M. G.}",

year = "1984",

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doi = "10.1007/BF00995696",

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volume = "33",

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T1 - Reaction of α-alkoxyacroleins with semicarbazide and its S-, Se-, and NH-analogs

AU - Keiko, N. A.

AU - Mamashvili, T. N.

AU - Rassolova, G. V.

AU - Kashik, T. V.

AU - Kalikhman, I. D.

AU - Vbronkov, M. G.

PY - 1984/1/1

Y1 - 1984/1/1

N2 - 1. The reaction of α-alkoxyacroleins with semi-, thiosemi-, and selenosemicarbazides in a basic medium leads to the formation of semi-, thiosemi-, and selenosemicarbazones of α-alkoxyacrolein. The reactions of α-ethoxyacroleins with twofold excess amounts of semi- and selenosemicarbazides in acid media lead to disemi- and diselenosemicarbazones of methylglyoxal. 2. Determination of basicity constants of semicarbazide and its S-, Se-, and NH-analogs was carried out in acetonitrile.

AB - 1. The reaction of α-alkoxyacroleins with semi-, thiosemi-, and selenosemicarbazides in a basic medium leads to the formation of semi-, thiosemi-, and selenosemicarbazones of α-alkoxyacrolein. The reactions of α-ethoxyacroleins with twofold excess amounts of semi- and selenosemicarbazides in acid media lead to disemi- and diselenosemicarbazones of methylglyoxal. 2. Determination of basicity constants of semicarbazide and its S-, Se-, and NH-analogs was carried out in acetonitrile.

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U2 - 10.1007/BF00995696

DO - 10.1007/BF00995696

M3 - Article

AN - SCOPUS:0042180400

SN - 0568-5230

VL - 33

SP - 561

EP - 564

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 3

ER -

Reaction of α-alkoxyacroleins with semicarbazide and its S-, Se-, and NH-analogs

Abstract

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