Reaction of acylacetylenes and methyl propiolate with N,N′-bis(dithiocarboxy)piperazine

V. N. Elokhina; A. S. Nakhmanovich; R. V. Karnaukhova; I. D. Kalikhman; O. B. Bannikova

doi:10.1007/BF00958862

Reaction of acylacetylenes and methyl propiolate with N,N′-bis(dithiocarboxy)piperazine

V. N. Elokhina, A. S. Nakhmanovich, R. V. Karnaukhova, I. D. Kalikhman, O. B. Bannikova

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of N,N′-bis(dithiocarboxy)piperazine with acetylenic ketones and methyl propiolate gave N,N′-bis(acylvinyldithiocarbo)- and N,N′ -bis(methoxy-carbonylvinyldithiocarbo)piperazines. Heating the compounds obtained with perchloric acid leads to intramolecular cyclization with the formation of N,N′ -bis[2-acyl(methoxycarbonyl)methyl-1,3-dithietanium]piperazine perchlorates.

Original language	English
Pages (from-to)	2390-2393
Number of pages	4
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	39
Issue number	11
DOIs	https://doi.org/10.1007/BF00958862
State	Published - 1 Nov 1990
Externally published	Yes

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General Chemistry

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title = "Reaction of acylacetylenes and methyl propiolate with N,N′-bis(dithiocarboxy)piperazine",

abstract = "The reaction of N,N′-bis(dithiocarboxy)piperazine with acetylenic ketones and methyl propiolate gave N,N′-bis(acylvinyldithiocarbo)- and N,N′ -bis(methoxy-carbonylvinyldithiocarbo)piperazines. Heating the compounds obtained with perchloric acid leads to intramolecular cyclization with the formation of N,N′ -bis[2-acyl(methoxycarbonyl)methyl-1,3-dithietanium]piperazine perchlorates.",

author = "Elokhina, \{V. N.\} and Nakhmanovich, \{A. S.\} and Karnaukhova, \{R. V.\} and Kalikhman, \{I. D.\} and Bannikova, \{O. B.\}",

year = "1990",

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doi = "10.1007/BF00958862",

language = "English",

volume = "39",

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journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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T1 - Reaction of acylacetylenes and methyl propiolate with N,N′-bis(dithiocarboxy)piperazine

AU - Elokhina, V. N.

AU - Nakhmanovich, A. S.

AU - Karnaukhova, R. V.

AU - Kalikhman, I. D.

AU - Bannikova, O. B.

PY - 1990/11/1

Y1 - 1990/11/1

N2 - The reaction of N,N′-bis(dithiocarboxy)piperazine with acetylenic ketones and methyl propiolate gave N,N′-bis(acylvinyldithiocarbo)- and N,N′ -bis(methoxy-carbonylvinyldithiocarbo)piperazines. Heating the compounds obtained with perchloric acid leads to intramolecular cyclization with the formation of N,N′ -bis[2-acyl(methoxycarbonyl)methyl-1,3-dithietanium]piperazine perchlorates.

AB - The reaction of N,N′-bis(dithiocarboxy)piperazine with acetylenic ketones and methyl propiolate gave N,N′-bis(acylvinyldithiocarbo)- and N,N′ -bis(methoxy-carbonylvinyldithiocarbo)piperazines. Heating the compounds obtained with perchloric acid leads to intramolecular cyclization with the formation of N,N′ -bis[2-acyl(methoxycarbonyl)methyl-1,3-dithietanium]piperazine perchlorates.

UR - https://www.scopus.com/pages/publications/34249919518

U2 - 10.1007/BF00958862

DO - 10.1007/BF00958862

M3 - Article

AN - SCOPUS:34249919518

SN - 0568-5230

VL - 39

SP - 2390

EP - 2393

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 11

ER -

Reaction of acylacetylenes and methyl propiolate with N,N′-bis(dithiocarboxy)piperazine

Abstract

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