Reaction of copper derivatives of monosubstituted acetylenes with benzoyl chloride

A. Kh Filippova; G. S. Lyashenko; I. D. Kalikhman; V. Yu Vitkovskii; G. G. Naumova; N. S. Vyazankin

doi:10.1007/BF00953500

Reaction of copper derivatives of monosubstituted acetylenes with benzoyl chloride

A. Kh Filippova, G. S. Lyashenko, I. D. Kalikhman, V. Yu Vitkovskii, G. G. Naumova, N. S. Vyazankin

Research output: Contribution to journal › Article › peer-review

Abstract

Depending on the substituents in the aroxyl group, the reaction of copper aroxypropynylides with benzoyl chloride can proceed in three directions and lead respectively to the formation of allenic γ-ketoethers,1,6-diaroxy-2,4-hexadiynes, or aryl benzoates. Copper phenoxyethynylide forms phenyl benzoate under these conditions.

Original language	English
Pages (from-to)	861-863
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	32
Issue number	4
DOIs	https://doi.org/10.1007/BF00953500
State	Published - 1 Jan 1983
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Reaction of copper derivatives of monosubstituted acetylenes with benzoyl chloride",

abstract = "Depending on the substituents in the aroxyl group, the reaction of copper aroxypropynylides with benzoyl chloride can proceed in three directions and lead respectively to the formation of allenic γ-ketoethers,1,6-diaroxy-2,4-hexadiynes, or aryl benzoates. Copper phenoxyethynylide forms phenyl benzoate under these conditions.",

author = "Filippova, {A. Kh} and Lyashenko, {G. S.} and Kalikhman, {I. D.} and Vitkovskii, {V. Yu} and Naumova, {G. G.} and Vyazankin, {N. S.}",

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T1 - Reaction of copper derivatives of monosubstituted acetylenes with benzoyl chloride

AU - Filippova, A. Kh

AU - Lyashenko, G. S.

AU - Kalikhman, I. D.

AU - Vitkovskii, V. Yu

AU - Naumova, G. G.

AU - Vyazankin, N. S.

PY - 1983/1/1

Y1 - 1983/1/1

N2 - Depending on the substituents in the aroxyl group, the reaction of copper aroxypropynylides with benzoyl chloride can proceed in three directions and lead respectively to the formation of allenic γ-ketoethers,1,6-diaroxy-2,4-hexadiynes, or aryl benzoates. Copper phenoxyethynylide forms phenyl benzoate under these conditions.

AB - Depending on the substituents in the aroxyl group, the reaction of copper aroxypropynylides with benzoyl chloride can proceed in three directions and lead respectively to the formation of allenic γ-ketoethers,1,6-diaroxy-2,4-hexadiynes, or aryl benzoates. Copper phenoxyethynylide forms phenyl benzoate under these conditions.

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U2 - 10.1007/BF00953500

DO - 10.1007/BF00953500

M3 - Article

AN - SCOPUS:34250154814

SN - 0568-5230

VL - 32

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EP - 863

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 4

ER -

Reaction of copper derivatives of monosubstituted acetylenes with benzoyl chloride

Abstract

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