Reaction of dimethyl(chloromethyl)chlorosilane with trimethylsilyl derivatives of l-phenyl-2-acetyl- and 1-phenyl-2-trifluoroacetylhydrazines

I. D. Kalikhman, O. B. Bannikova, L. I. Volkova, L. I. Belousova, T. I. Yushmanova, V. A. Lopyrev, O. A. Vyazankina, N. S. Vyazankin, V. A. Pestunovich

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Abstract

The reaction of dimethyl(chloromethyl)chlorosilane with the phenylhydrazone of 1-triraethylsiloxyethanone proceeds with initial trans-silylation and subsequent formation of (O→ Si)-chloro[2-(1-phenyl-2-acetylhydrazino)methyl]diraethylsilane. The analogous reaction with the phenylhydrazone of 1-trimethylsiloxy-2-trifluoroethanone terminates at the trans-silylation step.

Original languageEnglish
Pages (from-to)2550-2551
Number of pages2
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume35
Issue number12
DOIs
StatePublished - 1 Dec 1986
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)

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