Reaction of tetraethoxysilane and triethoxymethane with some α-substituted α, β-unsaturated aldehydes

M. G. Voronkov; N. A. Keiko; L. G. Stepanova; G. I. Kirillova; T. N. Musorina; I. D. Kalikhman

doi:10.1007/BF00922981

Reaction of tetraethoxysilane and triethoxymethane with some α-substituted α, β-unsaturated aldehydes

M. G. Voronkov, N. A. Keiko, L. G. Stepanova, G. I. Kirillova, T. N. Musorina, I. D. Kalikhman

Research output: Contribution to journal › Article › peer-review

Abstract

1. The reaction of α-halo-substituted α, β-unsaturated aldehydes with tetraethoxysilane and triethoxy-methane makes it possible to obtain their acetals in good yields. 2. The reaction of α-ethoxyacrolein with tetraethoxysilane and with triethoxymethane does not give the acetal, but instead either 2, 2-diethoxypropanal or 1,1,2,2,4,4-hexaethoxybutane.

Original language	English
Pages (from-to)	1111-1112
Number of pages	2
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	24
Issue number	5
DOIs	https://doi.org/10.1007/BF00922981
State	Published - 1 Jan 1975
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Reaction of tetraethoxysilane and triethoxymethane with some α-substituted α, β-unsaturated aldehydes",

abstract = "1. The reaction of α-halo-substituted α, β-unsaturated aldehydes with tetraethoxysilane and triethoxy-methane makes it possible to obtain their acetals in good yields. 2. The reaction of α-ethoxyacrolein with tetraethoxysilane and with triethoxymethane does not give the acetal, but instead either 2, 2-diethoxypropanal or 1,1,2,2,4,4-hexaethoxybutane.",

author = "Voronkov, {M. G.} and Keiko, {N. A.} and Stepanova, {L. G.} and Kirillova, {G. I.} and Musorina, {T. N.} and Kalikhman, {I. D.}",

year = "1975",

month = jan,

day = "1",

doi = "10.1007/BF00922981",

language = "English",

volume = "24",

pages = "1111--1112",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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number = "5",

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TY - JOUR

T1 - Reaction of tetraethoxysilane and triethoxymethane with some α-substituted α, β-unsaturated aldehydes

AU - Voronkov, M. G.

AU - Keiko, N. A.

AU - Stepanova, L. G.

AU - Kirillova, G. I.

AU - Musorina, T. N.

AU - Kalikhman, I. D.

PY - 1975/1/1

Y1 - 1975/1/1

N2 - 1. The reaction of α-halo-substituted α, β-unsaturated aldehydes with tetraethoxysilane and triethoxy-methane makes it possible to obtain their acetals in good yields. 2. The reaction of α-ethoxyacrolein with tetraethoxysilane and with triethoxymethane does not give the acetal, but instead either 2, 2-diethoxypropanal or 1,1,2,2,4,4-hexaethoxybutane.

AB - 1. The reaction of α-halo-substituted α, β-unsaturated aldehydes with tetraethoxysilane and triethoxy-methane makes it possible to obtain their acetals in good yields. 2. The reaction of α-ethoxyacrolein with tetraethoxysilane and with triethoxymethane does not give the acetal, but instead either 2, 2-diethoxypropanal or 1,1,2,2,4,4-hexaethoxybutane.

UR - http://www.scopus.com/inward/record.url?scp=34250397719&partnerID=8YFLogxK

U2 - 10.1007/BF00922981

DO - 10.1007/BF00922981

M3 - Article

AN - SCOPUS:34250397719

SN - 0568-5230

VL - 24

SP - 1111

EP - 1112

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 5

ER -

Reaction of tetraethoxysilane and triethoxymethane with some α-substituted α, β-unsaturated aldehydes

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