TY - CHAP
T1 - Reactions in Solid-State Inclusion Compounds
T2 - Supramolecular Reactivity
AU - Harris, Kenneth DM
AU - Palmer, Benjamin A
AU - Edwards-Gau, Gregory R
PY - 2012/3
Y1 - 2012/3
N2 - This chapter focuses on chemical reactions occurring within solid organic inclusion compounds, encompassing a broad range of inclusion compounds and a wide variety of different reaction types, including reactions of the guest molecules (such as dimerization, polymerization, cyclization, isomerization, and decomposition), reactions involving the host molecules, and guest exchange processes. In many cases, chemical transformations of guest molecules confined within solid host structures proceed with a high degree of selectivity toward a single product, and often with a high degree of stereoselectivity and/or enantioselectivity, as a consequence of the geometrical constraints imposed on the reacting molecules by the host structure. For this reason, the products obtained from such reactions are often significantly different from those obtained from the corresponding reactions in the solution state or in the “pure” crystalline phase of the guest molecules. Through the examples highlighted in this chapter, general issues relating to reactions in solid organic inclusion compounds are rationalized and discussed.
AB - This chapter focuses on chemical reactions occurring within solid organic inclusion compounds, encompassing a broad range of inclusion compounds and a wide variety of different reaction types, including reactions of the guest molecules (such as dimerization, polymerization, cyclization, isomerization, and decomposition), reactions involving the host molecules, and guest exchange processes. In many cases, chemical transformations of guest molecules confined within solid host structures proceed with a high degree of selectivity toward a single product, and often with a high degree of stereoselectivity and/or enantioselectivity, as a consequence of the geometrical constraints imposed on the reacting molecules by the host structure. For this reason, the products obtained from such reactions are often significantly different from those obtained from the corresponding reactions in the solution state or in the “pure” crystalline phase of the guest molecules. Through the examples highlighted in this chapter, general issues relating to reactions in solid organic inclusion compounds are rationalized and discussed.
U2 - 10.1002/9780470661345
DO - 10.1002/9780470661345
M3 - Chapter
SN - 9780470746400
T3 - Supramolecular Chemistry: From Molecules to Nanomaterials
SP - 1589
EP - 1612
BT - Supramolecular Chemistry
A2 - Gale, Philip A.
A2 - Steed, Jonathan W.
PB - Wiley Online Library
ER -