Reactions of α-alkoxy and α-piperidino α,β-unsaturated aldehydes with primary amines

N. A. Keiko; A. Yu Rulev; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF00959373

Reactions of α-alkoxy and α-piperidino α,β-unsaturated aldehydes with primary amines

N. A. Keiko
, A. Yu Rulev
, I. D. Kalikhman
, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of α-alkoxyacroleins with primary amines affords only Schiff bases, αPiperidinocrotonaldehyde reacts with alkylamines, forming a mixture of 1-(alkylamino)-2piperidino-2-butene, 1,2-bis(alkylamino)-butane, and N-formylpiperidine. Their correlation is determined by the reaction conditions and by the structure of the alkylamine.

Original language	English
Pages (from-to)	320-322
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	36
Issue number	2
DOIs	https://doi.org/10.1007/BF00959373
State	Published - 1 Jan 1987
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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abstract = "The reaction of α-alkoxyacroleins with primary amines affords only Schiff bases, αPiperidinocrotonaldehyde reacts with alkylamines, forming a mixture of 1-(alkylamino)-2piperidino-2-butene, 1,2-bis(alkylamino)-butane, and N-formylpiperidine. Their correlation is determined by the reaction conditions and by the structure of the alkylamine.",

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AU - Keiko, N. A.

AU - Rulev, A. Yu

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1987/1/1

Y1 - 1987/1/1

N2 - The reaction of α-alkoxyacroleins with primary amines affords only Schiff bases, αPiperidinocrotonaldehyde reacts with alkylamines, forming a mixture of 1-(alkylamino)-2piperidino-2-butene, 1,2-bis(alkylamino)-butane, and N-formylpiperidine. Their correlation is determined by the reaction conditions and by the structure of the alkylamine.

AB - The reaction of α-alkoxyacroleins with primary amines affords only Schiff bases, αPiperidinocrotonaldehyde reacts with alkylamines, forming a mixture of 1-(alkylamino)-2piperidino-2-butene, 1,2-bis(alkylamino)-butane, and N-formylpiperidine. Their correlation is determined by the reaction conditions and by the structure of the alkylamine.

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M3 - Article

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SN - 0568-5230

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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Reactions of α-alkoxy and α-piperidino α,β-unsaturated aldehydes with primary amines

Abstract

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