Reactivity-Selectivity Relationships. II. A Simple Model to Explain Nucleophile-Electrophile Combination Reactions and its Implications for the Reactivity-Selectivity Principle

Addy Pross

doi:10.1021/ja00419a023

Reactivity-Selectivity Relationships. II. A Simple Model to Explain Nucleophile-Electrophile Combination Reactions and its Implications for the Reactivity-Selectivity Principle

Addy Pross

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

A model designed to explain the mechanism of nucleophile-electrophile combination reactions based on solvation effects is presented, and the hitherto inexplicable N₊ correlation is rationalized. The model supports the reactivity-selectivity principle but emphasizes that solvation effects may mask its general applicability.

Original language	English
Pages (from-to)	776-778
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	98
Issue number	3
DOIs	https://doi.org/10.1021/ja00419a023
State	Published - 1 Feb 1976

ASJC Scopus subject areas

Catalysis
Chemistry (all)
Biochemistry
Colloid and Surface Chemistry

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title = "Reactivity-Selectivity Relationships. II. A Simple Model to Explain Nucleophile-Electrophile Combination Reactions and its Implications for the Reactivity-Selectivity Principle",

abstract = "A model designed to explain the mechanism of nucleophile-electrophile combination reactions based on solvation effects is presented, and the hitherto inexplicable N+ correlation is rationalized. The model supports the reactivity-selectivity principle but emphasizes that solvation effects may mask its general applicability.",

author = "Addy Pross",

year = "1976",

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N2 - A model designed to explain the mechanism of nucleophile-electrophile combination reactions based on solvation effects is presented, and the hitherto inexplicable N+ correlation is rationalized. The model supports the reactivity-selectivity principle but emphasizes that solvation effects may mask its general applicability.

AB - A model designed to explain the mechanism of nucleophile-electrophile combination reactions based on solvation effects is presented, and the hitherto inexplicable N+ correlation is rationalized. The model supports the reactivity-selectivity principle but emphasizes that solvation effects may mask its general applicability.

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Reactivity-Selectivity Relationships. II. A Simple Model to Explain Nucleophile-Electrophile Combination Reactions and its Implications for the Reactivity-Selectivity Principle

Abstract

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