Redox chemistry of ruthenium porphyrins: Evidence for internal electron transfer and the characterization of [RuIII(OEP+.)] species

Mark Barley, James Y. Becker, George Domazetis, David Dolphin, Brian R. James

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

An internal electron transfer process from ruthenium(II) to an octaethylporphyrin radical moiety is induced by changes in axial ligation, and the species formed by a two-electron oxidation of ruthenium(II) porphyrins is characterized as a ruthenium(III) porphyrin cation radical.

Original languageEnglish
Pages (from-to)982-983
Number of pages2
JournalChemical Communications
Issue number19
DOIs
StatePublished - 1 Jan 1981

ASJC Scopus subject areas

  • Molecular Medicine

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