Redox chemistry of ruthenium porphyrins: Evidence for internal electron transfer and the characterization of [RuIII(OEP+.)] species

Mark Barley; James Y. Becker; George Domazetis; David Dolphin; Brian R. James

doi:10.1039/C39810000982

Redox chemistry of ruthenium porphyrins: Evidence for internal electron transfer and the characterization of [Ru^III(OEP^+.)] species

Mark Barley, James Y. Becker, George Domazetis, David Dolphin, Brian R. James

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

An internal electron transfer process from ruthenium(II) to an octaethylporphyrin radical moiety is induced by changes in axial ligation, and the species formed by a two-electron oxidation of ruthenium(II) porphyrins is characterized as a ruthenium(III) porphyrin cation radical.

Original language	English
Pages (from-to)	982-983
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39810000982
State	Published - 1 Jan 1981

ASJC Scopus subject areas

Molecular Medicine

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title = "Redox chemistry of ruthenium porphyrins: Evidence for internal electron transfer and the characterization of [RuIII(OEP+.)] species",

abstract = "An internal electron transfer process from ruthenium(II) to an octaethylporphyrin radical moiety is induced by changes in axial ligation, and the species formed by a two-electron oxidation of ruthenium(II) porphyrins is characterized as a ruthenium(III) porphyrin cation radical.",

author = "Mark Barley and Becker, {James Y.} and George Domazetis and David Dolphin and James, {Brian R.}",

year = "1981",

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T2 - Evidence for internal electron transfer and the characterization of [RuIII(OEP+.)] species

AU - Barley, Mark

AU - Becker, James Y.

AU - Domazetis, George

AU - Dolphin, David

AU - James, Brian R.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - An internal electron transfer process from ruthenium(II) to an octaethylporphyrin radical moiety is induced by changes in axial ligation, and the species formed by a two-electron oxidation of ruthenium(II) porphyrins is characterized as a ruthenium(III) porphyrin cation radical.

AB - An internal electron transfer process from ruthenium(II) to an octaethylporphyrin radical moiety is induced by changes in axial ligation, and the species formed by a two-electron oxidation of ruthenium(II) porphyrins is characterized as a ruthenium(III) porphyrin cation radical.

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U2 - 10.1039/C39810000982

DO - 10.1039/C39810000982

M3 - Article

AN - SCOPUS:37049098896

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JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Redox chemistry of ruthenium porphyrins: Evidence for internal electron transfer and the characterization of [Ru^III(OEP^+.)] species

Abstract

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