Abstract
The effect of the giant Kohn anomaly in a one dimensional system on the optical reflectivity is calculated, for parameters believed to be characteristic for TTFTCNQ. It is found that the Kohn anomaly in the optical phonon branch due to stretching vibrations of the CN groups, whose unperturbed frequency is 2100-2200 cm-1, produces a minimum in the reflectivity at 1600 cm-, approximately. This minimum coincides with the minimum w found experimentally by Bright, Garito and Heeger. By this mechanism, phonons with a wavevector of order 2kF affect the reflectivity of photons with q ≈ 0.
Original language | English |
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Pages (from-to) | 849-853 |
Number of pages | 5 |
Journal | Solid State Communications |
Volume | 15 |
Issue number | 5 |
DOIs | |
State | Published - 1 Sep 1974 |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry (all)
- Condensed Matter Physics
- Materials Chemistry