Resonant Raman scattering by adsorbed molecules

Shlomo Efrima, Horia Metiu

Research output: Contribution to journalArticlepeer-review

71 Scopus citations

Abstract

We extend the classical model used in our previous work, to discuss the resonant Raman scattering by a molecule located near a metallic surface. We use the Drude model, modified to incorporate the electrodynamic effects of the surface. The frequency dependence of the polarizability is substantially modified and this lowers the frequency at which the resonant Raman effect appears. We derive the intensity of the fundamental and that of the overtones, for resonant scattering, and exemplify numerically their behavior.

Original languageEnglish
Pages (from-to)1939-1947
Number of pages9
JournalJournal of Chemical Physics
Volume70
Issue number4
DOIs
StatePublished - 1 Jan 1979
Externally publishedYes

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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