Response to V. A. Marichev's reply [Surf. Sci. 605(2011)2097] to the comments written by E. M. Gutman [Surf. Sci. 605(2011)1923]

Research output: Contribution to journalComment/debate

7 Scopus citations

Abstract

For the first time, it is shown that the first and second Gokhshtein equations were originally derived by him from false fundamental equations violating criteria for applications of Maxwell relations and Legendre transforms. These equations are erroneous. For example, the direct connection between the electrode potential and charge density is actually independent of the tangential elastic strain of flat ideally polarizable electrode. The sequence of equations of Shuttleworth-Herring-Eriksson-Couchman-Jesser-Everet- Davidson-Rusanov has a common mathematical defect which consists of illegally equating the total differential to the partial differential.

Original languageEnglish
Pages (from-to)772-775
Number of pages4
JournalSurface Science
Volume606
Issue number7-8
DOIs
StatePublished - 1 Jan 2012

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

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