Robust supramolecular heterosynthons in chiral ammonium carboxylate salts

Andreas Lemmerer; Susan A. Bourne; Manuel A. Fernandes

doi:10.1021/cg701020s

Robust supramolecular heterosynthons in chiral ammonium carboxylate salts

Andreas Lemmerer, Susan A. Bourne, Manuel A. Fernandes

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The ammonium carboxylate salts (m-iodobenzoate)·((R)-1- phenylethylammonium) (1), (m-iodobenzoate)·((S)-1-phenylethylammonium) (2), and (m-iodobenzoate)·((±)-1-phenylethylammonium) (3) self-assemble to form two types of one-dimensional hydrogen bonded columns, depending on the homo- or heterochirality of the cation: 1 and 2 form noncentrosymmetric hydrogen bonded columns having a 2-fold screw axis, whereas 3 forms centrosymmetric hydrogen bonded columns having an inversion center.

Original language	English
Pages (from-to)	1106-1109
Number of pages	4
Journal	Crystal Growth and Design
Volume	8
Issue number	4
DOIs	https://doi.org/10.1021/cg701020s
State	Published - 1 Apr 2008
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Robust supramolecular heterosynthons in chiral ammonium carboxylate salts",

abstract = "The ammonium carboxylate salts (m-iodobenzoate)·((R)-1- phenylethylammonium) (1), (m-iodobenzoate)·((S)-1-phenylethylammonium) (2), and (m-iodobenzoate)·((±)-1-phenylethylammonium) (3) self-assemble to form two types of one-dimensional hydrogen bonded columns, depending on the homo- or heterochirality of the cation: 1 and 2 form noncentrosymmetric hydrogen bonded columns having a 2-fold screw axis, whereas 3 forms centrosymmetric hydrogen bonded columns having an inversion center.",

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AU - Lemmerer, Andreas

AU - Bourne, Susan A.

AU - Fernandes, Manuel A.

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Y1 - 2008/4/1

N2 - The ammonium carboxylate salts (m-iodobenzoate)·((R)-1- phenylethylammonium) (1), (m-iodobenzoate)·((S)-1-phenylethylammonium) (2), and (m-iodobenzoate)·((±)-1-phenylethylammonium) (3) self-assemble to form two types of one-dimensional hydrogen bonded columns, depending on the homo- or heterochirality of the cation: 1 and 2 form noncentrosymmetric hydrogen bonded columns having a 2-fold screw axis, whereas 3 forms centrosymmetric hydrogen bonded columns having an inversion center.

AB - The ammonium carboxylate salts (m-iodobenzoate)·((R)-1- phenylethylammonium) (1), (m-iodobenzoate)·((S)-1-phenylethylammonium) (2), and (m-iodobenzoate)·((±)-1-phenylethylammonium) (3) self-assemble to form two types of one-dimensional hydrogen bonded columns, depending on the homo- or heterochirality of the cation: 1 and 2 form noncentrosymmetric hydrogen bonded columns having a 2-fold screw axis, whereas 3 forms centrosymmetric hydrogen bonded columns having an inversion center.

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U2 - 10.1021/cg701020s

DO - 10.1021/cg701020s

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VL - 8

SP - 1106

EP - 1109

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 4

ER -

Robust supramolecular heterosynthons in chiral ammonium carboxylate salts

Abstract

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